An article Recyclable Itaconic Acid with Water as Green Catalytic System: Synthesis of Substituted 1,5-Benzodiazepine Derivatives at Room Temperature WOS:000510247300016 published article about VERSATILE BUILDING-BLOCK; ONE-POT SYNTHESIS; BIOLOGICAL EVALUATION; EFFICIENT SYNTHESIS; 1,3-DIPOLAR CYCLOADDITION; ENVIRONMENTALLY BENIGN; O-PHENYLENEDIAMINE; ORGANIC-REACTIONS; FACILE SYNTHESIS; NANOCATALYST in [Tamuli, Kashyap J.; Bordoloi, Manobjyoti] North East Inst Sci & Technol, CSIR, Chem Sci & Technol Div, Jorhat 785006, Assam, India; [Tamuli, Kashyap J.; Bordoloi, Manobjyoti] Acad Sci & Innovat Res, Jorhat 785006, Assam, India in 2020.0, Cited 89.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. SDS of cas: 100-19-6
The construction of new C-N chemical bonds through co-condensation reaction in water media as sole solvent, especially without the use of any metal catalyst has undergoes green protocols. Herein, we describe a water-mediated and metal-free mild protocol for easily accessing of structurally and electronically diverse 1,5-benzodiazepine analogous by using biodegradable naturally occurring itaconic acid (20 mol%) in 30 minutes with excellent yields. The simplicity in reaction operation, reusability of the catalytic system and simple filtration to get the desired product make this reaction as green synthetic pathway upto multi gram scale level.
SDS of cas: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Tamuli, KJ; Bordoloi, M or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem