Recently I am researching about H BOND ACTIVATION; RU SINGLE BOND; AMIDO COMPLEXES; TITANIUM IMIDO; BASE-FREE; REACTIVITY; H-2; 2-(2-PYRIDYL)-1,8-NAPHTHYRIDINE; CYCLOADDITION; GENERATION, Saw an article supported by the ECOS-CONICYT (Action) [C14E02]; FondecytComision Nacional de Investigacion Cientifica y Tecnologica (CONICYT)CONICYT FONDECYT [1160505]; CONICYT-ChileComision Nacional de Investigacion Cientifica y Tecnologica (CONICYT); DICYT-USACH-Chile. Published in ELSEVIER SCIENCE SA in LAUSANNE ,Authors: Gajardo, J; Araya, JC; Ibanez, A; Guerchais, V; Le Bozec, H; Moya, SA; Aguirre, P. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. Quality Control of 1-(4-Nitrophenyl)ethanone
A new series of novel complexes of type cis-[Ru(CO)(2)Cl-2(L)(2)], L = 2-phenyl-1,8-naphthyridine, 2-(4′-nitrophenyl)-1,8-naphthyridine, 2-(4′-bromophenyl)-1,8-naphthyridine, 2-(4′-methylphenyl)-1,8-naphthyridine, 2-(3′-methoxyphenyl)-1,8-naphthyridine, 2-(2′-methoxyphenyl)-1,8-naphthyridine and 2-(4′-methoxyphenyl)-1,8-naphthyridine have been successfully synthesized and characterized. We found that the complexes can be directly synthesized from [RuCl2(CO)(2)](2) with high yield. The crystallographic structures of complex cis-[RuCl2(CO)(2)(2-(4′-methoxyphenyl)-1,8-naphthyridine-kappa N8)(2)] and cis-[RuCl2(CO)(2)(2-(2′-methoxyphenyl)-1,8-naphthyridine-kappa N8)(2)] have been established by X-ray single crystal diffraction studies, which indicate an octahedral geometry with two 1,8-naphthyridine ligands coordinated to the metal in a N-monodentate fashion. The ruthenium(II) complexes have been studied as catalysts in the transfer hydrogenation of acetophenone. We found that complexes show moderate activities and a 100% selectivity. The best turnover frequency (390 h(-1)) is found for cis-[RuCl2(CO)(2)(2-(4′-methoxyphenyl)-1,8-naphthyridine-kappa N8)(2)] when the substrate/catalysis ratio was 1000/1. The catalytic conditions were optimized using different substrate/catalyst and base/catalyst ratios.
Quality Control of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Gajardo, J; Araya, JC; Ibanez, A; Guerchais, V; Le Bozec, H; Moya, SA; Aguirre, P or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem