COA of Formula: C14H11N. In 2020 J AM CHEM SOC published article about PALLADIUM-CATALYZED 1,4-DIFUNCTIONALIZATION; LIGHT PHOTOREDOX CATALYSIS; CROSS-COUPLING REACTIONS; CARBON BOND FORMATION; DOMINO REACTIONS; HECK REACTION; C-C; CONJUGATED DIENES; ATOM-TRANSFER; HALIDES in [Huang, Huan-Ming; Bellotti, Peter; Pflueger, Philipp M.; Schwarz, J. Luca; Glorius, Frank] Westfalische Wilhelms Univ Munster, Organ Chem Inst, D-48149 Munster, Germany; [Heidrich, Bastian] Westfalische Wilhelms Univ Munster, MEET Battery Res Ctr, Inst Phys Chem, D-48149 Munster, Germany in 2020, Cited 139. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3.
Developing efficient and selective strategies to approach complex architectures containing (multi)stereogenic centers has been a long-standing synthetic challenge in both academia and industry. Catalytic cascade reactions represent a powerful means of rapidly leveraging molecular complexity from simple feedstocks. Unfortunately, carrying out cascade Heck-type reactions involving unactivated (tertiary) alkyl halides remains an unmet challenge owing to unavoidable beta-hydride elimination. Herein, we show that a modular, practical, and general palladium-catalyzed, radical three-component coupling can indeed overcome the aforementioned limitations through an interrupted Heck/allylic substitution sequence mediated by visible light. Selective 1,4-difunctionalization of unactivated 1,3-dienes, such as butadiene, has been achieved by employing different commercially available nitrogen-, oxygen-, sulfur-, or carbon-based nucleophiles and unactivated alkyl bromides (>130 examples, mostly >95:5 E/Z, >20:1 a). Sequential C(sp(3))-C(sp(3)) and C-X (N, O, S) bonds have been constructed efficiently with a broad scope and high functional group tolerance. The flexibility and versatility of the strategy have been illustrated in a gram-scale reaction and streamlined syntheses of complex ether, sulfone, and tertiary amine products, some of which would be difficult to access via currently established methods.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem