Category: benzodioxans. I found the field of Chemistry very interesting. Saw the article Chiral Sulfide Catalysis for Desymmetrizing Enantioselective Chlorination published in 2019, Reprint Addresses Zhao, XD (corresponding author), Sun Yat Sen Univ, Sch Chem, Inst Organ Chem, Guangzhou 510275, Guangdong, Peoples R China.; Zhao, XD (corresponding author), Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile.
An unprecendented chiral sulfide catalyzed desymmetrizing enantioselective chlorination is disclosed. Various aryl-tethered diolefins and diaryl-tethered olefins afforded teralins and tricyclic hexahydrophenalene derivatives, respectively, bearing multiple stereogenic centers in high yields with excellent enantio- and diastereoselectivities. In contrast, the tertiary amine catalyst (DHQD)(2)PHAL led to a diastereomeric product. The products could be transformed into a variety of compounds, such as spiro-N-heterocycles.
Category: benzodioxans. Welcome to talk about 86-29-3, If you have any questions, you can contact Cao, QX; Luo, J; Zhao, XD or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem