Category: benzodioxans. I found the field of Biochemistry & Molecular Biology; Chemistry very interesting. Saw the article Electrochemical Performance of ABNO for Oxidation of Secondary Alcohols in Acetonitrile Solution published in 2019.0, Reprint Addresses Shen, ZL; Li, MC (corresponding author), Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China.; Li, MC (corresponding author), Zhejiang Univ Technol, Res Ctr Anal & Measurement, Hangzhou 310032, Zhejiang, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.
The ketones was successfully prepared from secondary alcohols using 9-azabicyclo[3.3.1]nonane-N-oxyl (ABNO) as the catalyst and 2,6-lutidine as the base in acetonitrile solution. The electrochemical activity of ABNO for oxidation of 1-phenylethanol was investigated by cyclic voltammetry, in situ Fourier transform infrared spectroscopy (FTIR) and constant current electrolysis experiments. The resulting cyclic voltammetry indicated that ABNO exhibited much higher electrochemical activity when compared with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) under the similar conditions. A reasonable reaction mechanism of the electrocatalytic oxidation of 1-phenylethanol to acetophenone was proposed. In addition, a series of secondary alcohols could be converted to the corresponding ketones at room temperature in 80-95% isolated yields.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem