Application In Synthesis of 1-(4-Nitrophenyl)ethanone. I found the field of Chemistry very interesting. Saw the article An Umpolung Oxa-[2,3] Sigmatropic Rearrangement Employing Arynes for the Synthesis of Functionalized Enol Ethers published in 2021.0, Reprint Addresses Biju, AT (corresponding author), Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.
An oxa-[2,3] sigmatropic rearrangement involving arynes is reported featuring the umpolung of ketones, where the C = O bond polarity is reversed. The in situ-generated sulfur ylides from beta-keto thioethers and arynes undergo efficient rearrangement allowing the facile and robust synthesis of functionalized enol ethers in high yields and excellent functional group compatibility. Preliminary mechanistic studies rule out the possibility of Pummerer-type rearrangement operating in this case.
Welcome to talk about 100-19-6, If you have any questions, you can contact Gaykar, RN; George, M; Guin, A; Bhattacharjee, S; Biju, AT or send Email.. Application In Synthesis of 1-(4-Nitrophenyl)ethanone
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem