Safety of 1-(4-Nitrophenyl)ethanone. Recently I am researching about MUKAIYAMA-MICHAEL REACTIONS; SILYL ENOL ETHERS; ASYMMETRIC ALDOL; INTERMOLECULAR ADDITION; PROTODEAURATION STEP; EFFICIENT SYNTHESIS; PROPARGYLIC ESTERS; CARBONYL-COMPOUNDS; REACTION 40YEARS; REACTIVITY, Saw an article supported by the NSFNational Science Foundation (NSF) [CHE-1665122]; NIHUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USA [1R01GM120240-01]; University of South Florida Interdisciplinary NMR Facility; Chemical Purification, Analysis, and Screening core facility, the Department of Chemistry; College of Arts and Sciences. Published in CELL PRESS in CAMBRIDGE ,Authors: Yuan, T; Ye, XH; Zhao, PY; Teng, S; Yi, YP; Wang, J; Shan, C; Wojtas, L; Jean, J; Chen, H; Shi, X. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
A synergistic gold-iron (Au-Fe) catalytic system was developed for sequential alkyne hydration and vinyl Au addition to aldehydes or ketones. Fe(acac)(3) was identified as an essential co-catalyst in preventing vinyl Au protodeauration and facilitating nucleophilic additions. Effective C-C bond formation was achieved under mild conditions (room temperature) with excellent regioselectivity and high efficiency (1% [Au], up to 95% yields). The intramolecular reaction was also achieved, giving successful macrocyclization (16-31 ring sizes) with excellent yields (up to 90%, gram scale) without extended dilution (0.2 M), which highlights the great potential of this new crossed aldol strategy in challenging target molecule synthesis.
Welcome to talk about 100-19-6, If you have any questions, you can contact Yuan, T; Ye, XH; Zhao, PY; Teng, S; Yi, YP; Wang, J; Shan, C; Wojtas, L; Jean, J; Chen, H; Shi, X or send Email.. Safety of 1-(4-Nitrophenyl)ethanone
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem