I found the field of Chemistry very interesting. Saw the article Synergistic Catalysis of Se and Cu for the Activation of alpha-Hof Methyl Ketones with Molecular Oxygen/Alcohol to Produce alpha-KetoAcetals(dagger) published in 2020.0. Application In Synthesis of 1-(4-Nitrophenyl)ethanone, Reprint Addresses Yu, L (corresponding author), Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China.; Jiang, XF (corresponding author), East China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
Summary of main observation and conclusion Selenium and copper synergistically catalyzed the oxidation/alkoxylation of methyl ketones to synthesize alpha-keto acetals directly. Using O(2)as oxidant and alcohol as solvent and alkoxylation reagent, the reaction is practical from industrial viewpoint. Mechanistic studies revealed that copper promoted the oxidation of organoselenium intermediates with O(2)to allow the key rearrangement and selenoxidesyn-elimination regenerating the catalytically active organoselenium species.
Application In Synthesis of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Chen, C; Cao, ZC; Zhang, X; Li, YM; Yu, L; Jiang, XF or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem