Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner.In a patent, 22013-33-8, name is 2,3-Dihydrobenzo[b][1,4]dioxin-6-amine, introducing its new discovery. category: benzodioxans
An unexpected ring opening of 3-aminobenzofurans promoted by NaOtBu in hot toluene, leading to a variety of alpha-ketoimines, is described. In the presence of 3-iodobenzofurans, NaOtBu mediates the 3-aminobenzofurans ring opening via a possible radical pathway without the help of any external radical sources.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.category: benzodioxans, you can also check out more blogs about22013-33-8