An article Non-Heme-Type Ruthenium Catalyzed Chemo- and Site-Selective C-H Oxidation WOS:000516641100001 published article about NONHEME IRON CATALYSTS; BOND OXIDATION; ALKANE HYDROXYLATION; ATOM ECONOMY; COMPLEXES; OXYGENATION; FUNCTIONALIZATION; REACTIVITY; ACTIVATION; EVOLUTION in [Hayashi, Hiroki; Uchida, Tatsuya] Kyushu Univ, Fac Arts & Sci, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan; [Doiuchi, Daiki; Nakamura, Tatsuya] Kyushu Univ, Grad Sch Sci, Dept Chem, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan; [Uchida, Tatsuya] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI 12CNER, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan in 2020.0, Cited 86.0. Recommanded Product: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6
Herein, we developed a Ru(II)(BPGA) complex that could be used to catalyze chemo- and site-selective C-H oxidation. The described ruthenium complex was designed by replacing one pyridyl group on tris(2-pyridylmethyl)amine with an electron-donating amide ligand that was critical for promoting this type of reaction. More importantly, higher reactivities and better chemo-, and site-selectivities were observed for reactions using the cis-ruthenium complex rather than the trans-one. This reaction could be used to convert sterically less hindered methyne and/or methylene C-H bonds of a various organic substrates, including natural products, into valuable alcohol or ketone products.
Recommanded Product: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Doiuchi, D; Nakamura, T; Hayashi, H; Uchida, T or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem