An article Secondary amines as coupling partners in direct catalytic asymmetric reductive amination Electronic supplementary information (ESI) available: Procedures and spectra. WOS:000465341000014 published article about ALKYL-ARYL KETONES; IR-F-BINAPHANE; ENANTIOSELECTIVE HYDROGENATION; IDENTIFICATION; SALTS in [Wu, Zitong; Du, Shaozhi; Yang, Wenkun; Yang, Xiongyu; Huang, Haizhou; Chang, Mingxin] Northwest A&F Univ, Coll Chem & Pharm, Shanxi Key Lab Nat Prod & Chem Biol, 22 Xinong Rd, Yangling 712100, Shaanxi, Peoples R China; [Gao, Guorui] Shandong Normal Univ, Collaborat Innovat Ctr Functionalized Probes Chem, Univ Shandong, Coll Chem Chem Engn & Mat Sci, 88 Wenhuadong Rd, Jinan 250014, Shandong, Peoples R China in 2019.0, Cited 56.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Name: 1-(4-Nitrophenyl)ethanone
The secondary amine participating asymmetric reductive amination remains an unsolved problem in organic synthesis. Here we show for the first time that secondary amines are capable of effectively serving as N-sources in direct asymmetric reductive amination to afford corresponding tertiary chiral amines with the help of a selected additive set under mild conditions (0-25 degrees C). The applied chiral phosphoramidite ligands are readily prepared from BINOL and easily modified. Compared with common tertiary chiral amine synthetic methods, this procedure is much more concise and scalable, as exemplified by the facile synthesis of rivastigmine and N-methyl-1-phenylethanamine.
Welcome to talk about 100-19-6, If you have any questions, you can contact Wu, ZT; Du, SZ; Gao, GR; Yang, WK; Yang, XY; Huang, HZ; Chang, MX or send Email.. Name: 1-(4-Nitrophenyl)ethanone
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem