An article Palladium/Acid Relay Catalyzed Tandem Heck Coupling/6-Endo Cyclization between ortho-Halogenated Benzoates and Unactivated Terminal Alkenes for the Synthesis of 1-Isochromanones WOS:000461675600010 published article about INTRAMOLECULAR HYDROALKOXYLATION; CARBOXYLIC-ACIDS; TRIFLIC ACID; ARYL HALIDES; H BONDS; DERIVATIVES; ACTIVATION; OLEFINS; 3,4-DIHYDROISOCOUMARINS; PHYLLODULCIN in [Wen, Zhen-Kang; Ge, Xiao-Min; Zhao, Ze-Kai] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China; [Chao, Jian-Bin] Shanxi Univ, Sci Instrument Ctr, Taiyuan 030006, Shanxi, Peoples R China in 2019.0, Cited 67.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Computed Properties of C8H7NO3
We report a unique and expeditious route to synthesize 1-isochromanone derivatives through palladium catalyzed tandem Heck coupling/6-endo hydroacyloxylation cyclization between readily available ortho-halogenated benzoates and unactivated alkenes. Various 2-bromo or 2-iodo benzoates can be coupled efficiently with a broad range of alkenes to afford functionalized 1-isochromanones in high yields. Significantly, this cost-efficient and easy-to-handle synthetic methodology will have great prospect application in the synthetic and medicinal chemistry.
Welcome to talk about 100-19-6, If you have any questions, you can contact Wen, ZK; Ge, XM; Zhao, ZK; Chao, JB or send Email.. Computed Properties of C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem