Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 887144-97-0, Name is 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, molecular formula is , belongs to benzodioxans compound. In a document, author is Mironov, Vladimir F., Name: 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole.
The reaction of 4-(1,3,2-benzodioxaphosphol-2-yloxy)-3-tert-butylpent-4-en-2-one with hexafluoroacetone
Catalytic (ZnCl2, Et3N) phosphorylation of tert-butylacetyl-acetone with 2-chloro-1,3,2-benzodioxaphosphole unexpectedly occurs with elimination of proton from the methyl group and leads to vinyloxyphosphole derivative, viz., 4-(1,3,2-benzodioxa-phosphol-2-yloxy)-3-tert-butylpent-4-en-2-one. Its reaction with hexafluoroacetone gives a cage phosphorane as a result of subsequent chemoselective[4+2]- and [3 + 2]-cyclo-additions with stereoselectivity above 95%.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 887144-97-0, in my other articles. Name: 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem