An article Synthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation WOS:000537708200001 published article about ENANTIOSELECTIVE TRANSFER HYDROGENATION; P-BASED LIGANDS; DNA-BINDING; STRUCTURAL IDENTIFICATION; SCHIFF-BASE; ANTIBACTERIAL; BORON; COMPLEXES; ANTIOXIDANT; ACID in [Kilic, Ahmet; Balci, Tubba Ersayan] Harran Univ, Art & Sci Fac, Chem Dept, TR-63190 Sanliurfa, Turkey; [Arslan, Nevin] Sirnak Univ, Fac Agr, Dept Field Crops, TR-73000 Sirnak, Turkey; [Aydemir, Murat; Durap, Feyyaz] Dicle Univ, Sci Fac, Dept Chem, TR-21280 Diyarbakir, Turkey; [Okumu, Veysi] Univ Siirt, Fac Sci & Art, Dept Biol, TR-56100 Siirt, Turkey; [Tekin, Recep] Dicle Univ, Dept Infect Dis & Clin Microbiol, Fac Med, TR-21280 Diyarbakir, Turkey in 2020.0, Cited 69.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Product Details of 100-19-6
Two cis-1,2-diol-type chiral ligands (T-1 and T-2) and their tri-coordinated chiral dioxaborinane (T(1-2)B(1-2)) and four-coordinated chiral dioxaborinane adducts with 4-tert-butyl pyridine sustained by N -> B dative bonds (T(1-2)B(1-2)-N) were synthesized and characterized by various spectroscopic techniques such as NMR (H-1, C-13, and B-11), FT-IR and UV-Vis spectroscopy, LC-MS/MS, and elemental analysis. It was suggested that both ferrocene and trifluoromethyl groups played key roles in the catalytic and biological studies because they could tune the solubility of the chiral dioxaborinane complexes and adjust the strength of intermolecular interactions. To assess the biological activities of newly synthesized chiral dioxaborinane compounds, DPPH (2,2-diphenyl-1-picrylhydrazyl) radical scavenging, reducing power, antibacterial, DNA binding, and DNA cleavage activities were tested. Then, all chiral dioxaborinane complexes were investigated as catalysts for the asymmetric transfer hydrogenation of various ketones under suitable conditions. The results indicated that the chiral dioxaborinane catalysts performed well with high yields.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem