Recently I am researching about TRANS-HYDROBORATION; HYDRIDE; ALKENES; REDUCTION; COMPLEXES; EFFICIENT; IMINES, Saw an article supported by the . SDS of cas: 86-29-3. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Sarkar, N; Bera, S; Nembenna, S. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile
The reaction of LH [L = {(ArNH)(ArN)-C=N-C=(NAr)(NHAr)}; Ar =2,6-Et-2-C6H3] with a commercially available alane amine adduct (H3Al center dot NMe2Et) in toluene resulted in the formation of a conjugated bis-guanidinate (CBG)-supported aluminum dihydride complex, i.e., LAIH(2) (1), in good yield. The new complex has been thoroughly characterized by multinuclear magnetic resonance, IR, mass, and elemental analyses, including single-crystal structural studies. Further, we have demonstrated the aluminum-catalyzed hydroboration of a variety of nitriles and alkynes. Moreover, aluminum-catalyzed hydroboration is expanded to more challenging substrates such as alkene, pyridine, imine, carbodiimide, and isocyanides. More importantly, we have shown that the aluminum dihydride catalyzed both intra- and intermolecular chemoselective hydroboration of nitriles and alkynes over other reducible functionalities for the first time.
SDS of cas: 86-29-3. Welcome to talk about 86-29-3, If you have any questions, you can contact Sarkar, N; Bera, S; Nembenna, S or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem