An article Efficient and Practical Transfer Hydrogenation of Ketones Catalyzed by a Simple Bidentate Mn-NHC Complex WOS:000474698500001 published article about ASYMMETRIC TRANSFER HYDROGENATION; HETEROCYCLIC CARBENE COMPLEXES; MANGANESE; LIGANDS; RUTHENIUM; MECHANISM; ACETOPHENONE; REDUCTION; IRIDIUM; RHODIUM in [van Putten, Robbert; Benschop, Joeri; de Munck, Vincent J.; Filonenko, Georgy A.; Pidko, Evgeny A.] Delft Univ Technol, Fac Sci Appl, Inorgan Syst Engn Grp, Dept Chem Engn, Maasweg 9, NL-2629 HZ Delft, Netherlands; [Weber, Manuela; Mueller, Christian] Free Univ Berlin, Inst Chem & Biochem, Fabeckstr 34-36, D-14195 Berlin, Germany in 2019.0, Cited 42.0. Category: benzodioxans. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6
Catalytic reductions of carbonyl-containing compounds are highly important for the safe, sustainable, and economical production of alcohols. Herein, we report on the efficient transfer hydrogenation of ketones catalyzed by a highly potent Mn(I)-NHC complex. Mn-NHC 1 is practical at metal concentrations as low as 75 ppm, thus approaching loadings more conventionally reserved for noble metal based systems. With these low Mn concentrations, catalyst deactivation is found to be highly temperature dependent and becomes especially prominent at increased reaction temperature. Ultimately, understanding of deactivation pathways could help close the activity/stability-gap with Ru and Ir catalysts towards the practical implementation of sustainable earth-abundant Mn-complexes.
Category: benzodioxans. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact van Putten, R; Benschop, J; de Munck, VJ; Weber, M; Muller, C; Filonenko, GA; Pidko, EA or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem