Because a catalyst decreases the height of the energy barrier, 214894-89-0, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.214894-89-0, Name is 5-(Bromomethyl)-2,3-dihydro-1,4-benzodioxine, molecular formula is C9H9BrO2. In a article£¬once mentioned of 214894-89-0
Merging Photochemistry with Electrochemistry: Functional-Group Tolerant Electrochemical Amination of C(sp3)?H Bonds
Direct amination of C(sp3)?H bonds is of broad interest in the realm of C?H functionalization because of the prevalence of nitrogen heterocycles and amines in pharmaceuticals and natural products. Reported here is a combined electrochemical/photochemical method for dehydrogenative C(sp3)?H/N?H coupling that exhibits good reactivity with both sp2 and sp3 N?H bonds. The results show how use of iodide as an electrochemical mediator, in combination with light-induced cleavage of intermediate N?I bonds, enables the electrochemical process to proceed at low electrode potentials. This approach significantly improves the functional-group compatibility of electrochemical C?H amination, for example, tolerating electron-rich aromatic groups that undergo deleterious side reactions in the presence of high electrode potentials.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. 214894-89-0, In my other articles, you can also check out more blogs about 214894-89-0
Reference£º
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem