Cao, QX; Luo, J; Zhao, XD in [Cao, Qingxiang; Luo, Jie; Zhao, Xiaodan] Sun Yat Sen Univ, Sch Chem, Inst Organ Chem, Guangzhou 510275, Guangdong, Peoples R China; [Cao, Qingxiang; Luo, Jie; Zhao, Xiaodan] Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China published Chiral Sulfide Catalysis for Desymmetrizing Enantioselective Chlorination in 2019, Cited 81. Recommanded Product: 86-29-3. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3.
An unprecendented chiral sulfide catalyzed desymmetrizing enantioselective chlorination is disclosed. Various aryl-tethered diolefins and diaryl-tethered olefins afforded teralins and tricyclic hexahydrophenalene derivatives, respectively, bearing multiple stereogenic centers in high yields with excellent enantio- and diastereoselectivities. In contrast, the tertiary amine catalyst (DHQD)(2)PHAL led to a diastereomeric product. The products could be transformed into a variety of compounds, such as spiro-N-heterocycles.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem