2879-20-1, Name is 1-(2,3-Dihydrobenzo[b][1,4]dioxin-6-yl)ethanone, belongs to benzodioxans compound, is a common compound. Product Details of 2879-20-1In an article, once mentioned the new application about 2879-20-1.
Copper/Persulfate-Promoted Oxidative Decarboxylative C?H Acylation of Pyrazolones with alpha-Oxocarboxylic Acids: Direct Access to 4-Acylpyrazolones under Mild Conditions
A facile and efficient oxidative C?H acylation of N-substituted pyrazolones using alpha-oxocarboxylic acids as an acyl group source was developed. A combination of Cu(OAc)2 and K2S2O8 enables the reaction to proceed smoothly under air and provides a wide array of 4-acylpyrazolone products in moderate to excellent yields. The mechanism of this transformation is believed to proceed via a copper-induced decarboxylation to form the acyl-copper species. This method provides a convenient and useful route for a direct installation of an acyl moiety into bioactive pyrazolone derivatives, which can be further utilized in many applications. (Figure presented.).
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Reference£º
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem