Application In Synthesis of 1-(4-Nitrophenyl)ethanone. Han, ZW; Lv, JG; Zhang, JM in [Han, Ziwei; Lv, Jianguang; Zhang, Jianmin] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China; [Zhang, Jianmin] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China published One-pot synthesis of 2-amino-3,4-dicyanopyridines from ketoximes and tetracyanoethylene via Cu(I)-catalyzed cyclization in 2019.0, Cited 61.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A novel approach to 2-amino-3,4-dicyanopyridines has been discovered from Cu(I)-catalyzed cyclizations of simple and easily available ketoximes and tetracyanoethylene (TCNE). The complexed radical mechanism involves cleavage of several O-H/N-O/C-H bonds, and new C-C/C-N bonds formation. A wide variety of substrates with different functional groups could be smoothly converted into the corresponding products in moderate yields. (C) 2019 Elsevier Ltd. All rights reserved.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem