The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Cross-Electrophile C(sp2)-Si Coupling of Vinyl Chlorosilanes, the main research direction is cross electrophile coupling vinyl chloro silane carbon silicon bond; cross-coupling; nickel; organosilanes; reductive coupling; vinylsilanes.Category: benzodioxans.
The cross-electrophile coupling has become a powerful tool for C-C bond formation, but its potential for forging the C-Si bond remains unexplored. Here we report a cross-electrophile Csp2-Si coupling reaction of vinyl/aryl electrophiles with vinyl chlorosilanes. This new protocol offers an approach for facile and precise synthesis of organosilanes with high mol. diversity and complexity from readily available materials. The reaction proceeds under mild and non-basic conditions, demonstrating a high step economy, broad substrate scope, wide functionality tolerance, and easy scalability. The synthetic utility of the method is shown by its efficient accessing of silicon bioisosteres, the design of new BCB-monomers, and studies on the Hiyama cross-coupling of vinylsilane products.
In addition to the literature in the link below, there is a lot of literature about this compound(5,5′-Dimethyl-2,2′-bipyridine)Category: benzodioxans, illustrating the importance and wide applicability of this compound(1762-34-1).