An article Design of Manganese Phenol Pi-complexes as Shvo-type Catalysts for Transfer Hydrogenation of Ketones WOS:000463960000006 published article about ASYMMETRIC HYDROGENATION; IRON; EFFICIENT; MECHANISM; CHEMISTRY; ALDEHYDES; NITRILES; ALCOHOLS; LIGANDS; METALS in [Shvydkiy, Nikita, V; Nelyubina, Yulia, V; Perekalin, Dmitry S.] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, 28 Vavilova, Moscow 119991, Russia; [Vyhiyskyi, Oleksandr] Lomonosov Moscow State Univ, Dept Chem, 1-3 Leninskie Gory, Moscow 119991, Russia; [Perekalin, Dmitry S.] Plekhanov Russian Univ Econ, 36 Stremyannyi Pereulok, Moscow 117997, Russia in 2019.0, Cited 55.0. Name: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6
Catalytic hydrogenation is one of the most important reactions both in academic research and industry. We explored ability of the manganese pi-complexes to act as Shvo-type catalysts for transfer hydrogenation of ketones. DFT calculations suggested that the transfer of hydrogen atoms from the hypothetical intermediate [(C6Me3H2OH)Mn(CO)(2)H] to acetone has low activation barrier of 10.9 kcal mol(-1). Experimentally a number of ketones with various functional groups (OMe, NH2, Cl, CF3, pyridyl) were successfully reduced in isopropanol at 90 degrees C in the presence of the complex[(C6Me3H2OH)Mn(CO)(3)]BF4 (1 mol %) and (BuOK)-Bu-t (75 mol %). However, further investigation revealed that the reduction was mainly promoted by base rather than the manganese complex.
Name: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Shvydkiy, NV; Vyhiyskyi, O; Nelyubina, YV; Perekalin, DS or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem