Luo, XL; He, RF; Liu, Q; Gao, YP; Li, JQ; Chen, XW; Zhu, ZZ; Huang, YB; Li, YB in [Luo, Xianglin; He, Runfa; Liu, Qiang; Gao, Yanping; Li, Jingqing; Chen, Xiuwen; Zhu, Zhongzhi; Huang, Yubing; Li, Yibiao] Wuyi Univ, Sch Biotechnol & Hlth Sci, Jiangmen 529090, Guangdong, Peoples R China; [Liu, Qiang] Tsinghua Univ, Ctr Basic Mol Sci, Dept Chem, Beijing 100084, Peoples R China published Metal-Free Oxidative Esterification of Ketones and Potassium Xanthates: Selective Synthesis of alpha-Ketoesters and Esters in 2020, Cited 74. Recommanded Product: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A novel and efficient oxidative esterification for the selective synthesis of alpha-ketoesters and esters has been developed under metal-free conditions. In the protocol, various alpha-ketoesters and esters are available in high yields from commercially available ketones and potassium xanthates. Mechanistic studies have proven that potassium xanthate not only promotes oxidative esterification but also provides an alkoxy moiety for the reaction, which involves the cleavage and reconstruction of C-O bonds.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem