Reference of 6606-65-1, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 6606-65-1, Name is Butyl 2-cyanoacrylate, SMILES is C=C(C#N)C(OCCCC)=O, belongs to benzodioxans compound. In a article, author is Mironov, Vladimir F., introduce new discover of the category.
The reaction of 4-(1,3,2-benzodioxaphosphol-2-yloxy)-3-tert-butylpent-4-en-2-one with hexafluoroacetone
Catalytic (ZnCl2, Et3N) phosphorylation of tert-butylacetyl-acetone with 2-chloro-1,3,2-benzodioxaphosphole unexpectedly occurs with elimination of proton from the methyl group and leads to vinyloxyphosphole derivative, viz., 4-(1,3,2-benzodioxa-phosphol-2-yloxy)-3-tert-butylpent-4-en-2-one. Its reaction with hexafluoroacetone gives a cage phosphorane as a result of subsequent chemoselective[4+2]- and [3 + 2]-cyclo-additions with stereoselectivity above 95%.
Reference of 6606-65-1, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 6606-65-1 is helpful to your research.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem