Authors Malan, FP; Singleton, E; van Rooyen, PH; Albrecht, M; Landman, M in AMER CHEMICAL SOC published article about N-HETEROCYCLIC CARBENES; IRIDIUM COMPLEXES; COORDINATION; ACTIVATION; LIGANDS; REMOTE; RU; IMIDAZOLIUM; OXIDATION; BEHAVIOR in [Malan, Frederick P.; Singleton, Eric; van Rooyen, Petrus H.; Landman, Marile] Univ Pretoria, Dept Chem, 02 Lynnwood Rd, ZA-0002 Pretoria, South Africa; [Albrecht, Martin] Univ Bern, Dept Chem & Biochem, Freiestr 3, CH-3012 Bern, Switzerland in 2019.0, Cited 46.0. Name: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6
A series of p-cymene and cyclopentadienyl Ru(II)-aNHC complexes were synthesized from 2-methylimidazolium salts with either an N-bound alkenyl (1, 3) or picolyl tether (6, 7). The C(5)-Me substituted alkenyl-tethered analogues (2, 4) were also synthesized. Ag-mediated C(2)-dealkylation was a prominent side reaction that led to the formation of normally bound NHC Ru(II) complexes, which in selected cases were isolated (5, 8). A C(4)- over C(2)-selectivity for ruthenium binding was established by protecting the C(2)-position with an iPr group on the imidazolium precursor, for which unique p-cymene (9) and cyclopentadienyl (10) Ru(II)-aNHC derivatives were synthesized. All complexes were applied in the transfer hydrogenation of ketones and in secondary alcohol oxidation, with higher catalytic activity for the p-cymene over the cyclopentadienyl systems, as well as the alkenyl- over the picolyl-containing aNHC complexes.
Name: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Malan, FP; Singleton, E; van Rooyen, PH; Albrecht, M; Landman, M or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem