Liu, ZS; Zhang, WJ; Guo, S; Zhu, J in [Liu, Zhongsu; Zhang, Wenjing; Guo, Shan; Zhu, Jin] Nanjing Univ, Nanjing Natl Lab Microstruct, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210023, Jiangsu, Peoples R China published Spiro[indene-1,4 ‘-oxa-zolidinones] Synthesis via Rh(III)-Catalyzed Coupling of 4-Phenyl-1,3-oxazol-2(3H)-ones with Alkynes: A Redox-Neutral Approach in 2019.0, Cited 71.0. HPLC of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
Transition-metal-catalyzed C-H activation synthesis of heterocyclic spiro[4,4]nonanes has persistently witnessed the use of additional stoichiometric transition-metal oxidant when employing C=C bond as the Spiro ring closure site. Herein, we have addressed the issue by reporting a redox-neutral strategy for spiro[indene-1,4′-oxa-zolidinones] synthesis via Rh(III)-catalyzed coupling of 4-phenyl-1,3-oxazol-2(3H)-ones with alkynes. The synthesis features a broad substrate scope and high regiospecificity.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem