Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Angewandte Chemie, International Edition called Reductive Alkylation of Alkenyl Acetates with Alkyl Bromides by Nickel Catalysis, Author is He, Rong-De; Bai, Yunfei; Han, Guan-Yu; Zhao, Zhen-Zhen; Pang, Xiaobo; Pan, Xiaobo; Liu, Xue-Yuan; Shu, Xing-Zhong, which mentions a compound: 1762-34-1, SMILESS is CC1=CN=C(C=C1)C1=NC=C(C)C=C1, Molecular C12H12N2, Application In Synthesis of 5,5′-Dimethyl-2,2′-bipyridine.
Herein a cross-electrophile reaction of alkenyl acetates with alkyl bromides was reported. This work has enabled a new method for the synthesis of aliphatic alkenes from alkenyl acetates to be established that was used to add more structural complexity and mol. diversity with enhanced functionality tolerance. The method allows for a gram-scale reaction and modification of biol. active mols., and it affords access to useful building blocks. Preliminary mechanistic studies revealed that the Ni(I) species plays an essential role for the success of the coupling of these two reactivity-mismatched electrophiles.
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