An article A Common, Facile and Eco-Friendly Method for the Reduction of Nitroarenes, Selective Reduction of Poly-Nitroarenes and Deoxygenation of N-Oxide Containing Heteroarenes Using Elemental Sulfur WOS:000522338200008 published article about METAL-FREE REDUCTION; AQUEOUS AMMONIUM SULFIDE; NITRO-COMPOUNDS; EFFICIENT DEOXYGENATION; CATALYZED REDUCTION; GENERAL-METHOD; DERIVATIVES; HYDROGENATION; AMINES; PYRIDINE in [Romero, Angel H.; Cerecetto, Hugo] Univ Republica, Inst Quim Biol, Fac Ciencias, Igual 4225, Montevideo 11400, Uruguay in 2020.0, Cited 124.0. Recommanded Product: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6
A transition metal-free, environment-friendly and practical protocol was developed either for the reduction of nitroarenes or for the deoxygenation of N-oxide containing heteroarenes. The reaction proceeded with the use of a non-toxic and cheap feedstock as elemental sulfur in aqueous methanol under relatively mild conditions. Green chemistry credentials were widely favorable compared to traditional and industrial protocols with good E-factors and a low production of waste. The strategy allowed the efficient reduction of a large variety of substituted-nitroarenes including various o-nitroanilines as well as selective reduction of various poly-nitroarenes in excellent yields with a broad substrate scope. The protocol was successfully extended to the deoxygenation of some N-oxide containing heteroarenes, like benzofuroxans, phenazine N,N-‘-dioxides, pyridine N-oxides, 2H-indazole N-1-oxides, quinoxaline N-1,N-4-dioxides and benzo[d]imidazole N-1,N-3-dioxides. A gram-scale example for the synthesis of luminol, in green conditions, was reported. A solid mechanism of reaction was proposed from experimental evidences.
Recommanded Product: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Romero, AH; Cerecetto, H or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem