Name: 1-(4-Nitrophenyl)ethanone. In 2021.0 EUR J ORG CHEM published article about ASYMMETRIC HYDROGENATION; NITRO-COMPOUNDS; REDUCTION; COMPLEXES; PORPHYRIN; NITRILES; IMATINIB; SENSORS; C=O; CO in [Timelthaler, Daniel; Topf, Christoph] Johannes Kepler Univ JKU, Inst Catalysis INCA, A-4040 Linz, Austria; [Schoefberger, Wolfgang] Johannes Kepler Univ JKU, Inst Organ Chem, A-4040 Linz, Austria in 2021.0, Cited 61.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
We report on the first cobalt corrole that effectively mediates the homogeneous hydrogenation of structurally diverse nitroarenes to afford the corresponding amines. The given catalyst is easily assembled prior to use from 4-tert-butylbenzaldehyde and pyrrole followed by metalation of the resulting corrole macrocycle with cobalt(II) acetate. The thus-prepared complex is self-contained in that the hydrogenation protocol is free from the requirement for adding any auxiliary reagent to elicit the catalytic activity of the applied metal complex. Moreover, a containment system is not required for the assembly of the hydrogenation reaction set-up as both the autoclave and the reaction vessels are readily charged under a regular laboratory atmosphere.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem