Recommanded Product: 100-19-6. In 2020.0 CHEM-US published article about MUKAIYAMA-MICHAEL REACTIONS; SILYL ENOL ETHERS; ASYMMETRIC ALDOL; INTERMOLECULAR ADDITION; PROTODEAURATION STEP; EFFICIENT SYNTHESIS; PROPARGYLIC ESTERS; CARBONYL-COMPOUNDS; REACTION 40YEARS; REACTIVITY in [Yuan, Teng; Ye, Xiaohan; Teng, Shun; Wang, Jin; Shan, Chuan; Wojtas, Lukasz; Jean, Jonathan; Shi, Xiaodong] Univ S Florida, Dept Chem, Tampa, FL 33620 USA; [Zhao, Pengyi; Chen, Hao] New Jersey Inst Technol, Dept Chem & Environm Sci, Newark, NJ 07102 USA; [Yi, Yaping] Tsinghua Univ, Dept Chem, Beijing, Peoples R China in 2020.0, Cited 93.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A synergistic gold-iron (Au-Fe) catalytic system was developed for sequential alkyne hydration and vinyl Au addition to aldehydes or ketones. Fe(acac)(3) was identified as an essential co-catalyst in preventing vinyl Au protodeauration and facilitating nucleophilic additions. Effective C-C bond formation was achieved under mild conditions (room temperature) with excellent regioselectivity and high efficiency (1% [Au], up to 95% yields). The intramolecular reaction was also achieved, giving successful macrocyclization (16-31 ring sizes) with excellent yields (up to 90%, gram scale) without extended dilution (0.2 M), which highlights the great potential of this new crossed aldol strategy in challenging target molecule synthesis.
Welcome to talk about 100-19-6, If you have any questions, you can contact Yuan, T; Ye, XH; Zhao, PY; Teng, S; Yi, YP; Wang, J; Shan, C; Wojtas, L; Jean, J; Chen, H; Shi, X or send Email.. Recommanded Product: 100-19-6
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem