The transformation of simple hydrocarbons into more complex and valuable products has revolutionised modern synthetic chemistry. This type of reactivity has quickly become one of the cornerstones of modern catalysis.HPLC of Formula: C9H9BrO2, In a article, mentioned the application of 214894-89-0, molecular formula is C9H9BrO2
A new umpolung for direct gamma-regioselective nucleophilic addition of alcohols to gamma-enolizable alpha,beta-unsaturated aldehydes
A direct gamma-regioselective nucleophilic addition of alcohols toward gamma-enolizable alpha,beta-unsaturated aldehydes was developed using a catalytic amount of MeSO3H (30?mol%) and a stoichiometric amount of chloranil (1.0?equiv) as the oxidant. The addition of hexafluoroisopropanol (HFIP) was found to accelerate this cross-dehydrogenative coupling, furnishing diverse alcoholic adducts with high gamma-regio- and E-stereoselectivities.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. HPLC of Formula: C9H9BrO2, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 214894-89-0, in my other articles.
Reference£º
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem