Recommanded Product: 100-19-6. In 2020 MOLECULES published article about N-H INDOLES; ASYMMETRIC-SYNTHESIS; 3+2 CYCLOADDITION; ONE-POT; 3-NITROINDOLES; ACYLATION; 3-ACYLINDOLES; REARRANGEMENT; CONSTRUCTION; 3-AROYLINDOLES in [Tejedor, David; Diana-Rivero, Raquel; Garcia-Tellado, Fernando] Inst Prod Nat & Agrobiol, Consejo Super Invest Cient, Astroffs Francisco Sanchez 3, San Cristobal la Laguna 38206, Spain; [Diana-Rivero, Raquel] Univ La Laguna, Doctoral & Postgrad Sch, Apartado Postal 456, San Cristobal la Laguna 38200, Spain in 2020, Cited 84. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A consecutive 2-step synthesis of N-unprotected polysubstituted indoles bearing an electron-withdrawing group at the C-3 position from readily available nitroarenes is reported. The protocol is based on the [3,3]-sigmatropic rearrangement of N-oxyenamines generated by the DABCO-catalyzed reaction of N-arylhydroxylamines and conjugated terminal alkynes, and delivers indoles endowed with a wide array of substitution patterns and topologies.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem