Authors Wang, DQ; Hou, GH; Zi, GF; Walter, MD in AMER CHEMICAL SOC published article about SMALL-MOLECULE ACTIVATION; H BOND ACTIVATION; TRANSITION-METAL; TERMINAL PHOSPHINIDENE; IMIDO METALLOCENE; FORMING REACTIONS; RARE-EARTH; COMPLEXES; ACTINIDE; THORIUM in [Wang, Deqiang; Hou, Guohua; Zi, Guofu] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China; [Walter, Marc D.] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany in 2021, Cited 131. Formula: C14H11N. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3
This paper describes the synthesis, structure, and reactivity of (eta(5)-C5Me5)(2)U(=-P-2,4,6-(Pr3C6H2)-Pr-i)(OPPh3) (2). Compound 2 can be accessed by a salt metathesis reaction of the uranium methyl chloride metallocene (eta(5)-C5Me5)(2)U(Cl)Me (1) with 2,4,6-(Pr3C6H2PHK)-Pr-i in toluene in the presence of Ph3PO at ambient temperature. Furthermore, it reacts as a masked synthon for the divalent uranium fragment (eta(5)-C5Me5)(2)U by elimination of the phosphinidene fragment (2,4,6-(Pr3C6H2P)-Pr-i:) on exposure to small organic molecules such as Ph2S2, Ph2Se2, bipy, ketazines, carbodiimides, diazenes, and organic azides. Nevertheless, it also forms carbodithioates, imido, diiminatos, and metallaaziridines when it is treated with isothiocyanate, nitrites, and isonitriles, respectively. In contrast, after addition of Me,SiN 3 the uranium azido species (eta(5)-C5Me5)(2)U[N(SiMe3)P(2-NHCMe2-4,6-(Pr2C6H2)-Pr-i)N(SiMe3)]-(N-3) (13) is isolated in good yield.
Formula: C14H11N. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem