So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Duan, Jicheng; Wang, Ke; Xu, Guang-Li; Kang, Shaolin; Qi, Liangliang; Liu, Xue-Yuan; Shu, Xing-Zhong researched the compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ).Formula: C12H12N2.They published the article 《Cross-Electrophile C(sp2)-Si Coupling of Vinyl Chlorosilanes》 about this compound( cas:1762-34-1 ) in Angewandte Chemie, International Edition. Keywords: cross electrophile coupling vinyl chloro silane carbon silicon bond; cross-coupling; nickel; organosilanes; reductive coupling; vinylsilanes. We’ll tell you more about this compound (cas:1762-34-1).
The cross-electrophile coupling has become a powerful tool for C-C bond formation, but its potential for forging the C-Si bond remains unexplored. Here we report a cross-electrophile Csp2-Si coupling reaction of vinyl/aryl electrophiles with vinyl chlorosilanes. This new protocol offers an approach for facile and precise synthesis of organosilanes with high mol. diversity and complexity from readily available materials. The reaction proceeds under mild and non-basic conditions, demonstrating a high step economy, broad substrate scope, wide functionality tolerance, and easy scalability. The synthetic utility of the method is shown by its efficient accessing of silicon bioisosteres, the design of new BCB-monomers, and studies on the Hiyama cross-coupling of vinylsilane products.
This literature about this compound(1762-34-1)Formula: C12H12N2has given us a lot of inspiration, and I hope that the research on this compound(5,5′-Dimethyl-2,2′-bipyridine) can be further advanced. Maybe we can get more compounds in a similar way.