SDS of cas: 100-19-6. I found the field of Chemistry very interesting. Saw the article Regioselective Crossed Aldol Reactions under Mild Conditions via Synergistic Gold-Iron Catalysis published in 2020.0, Reprint Addresses Shi, X (corresponding author), Univ S Florida, Dept Chem, Tampa, FL 33620 USA.; Chen, H (corresponding author), New Jersey Inst Technol, Dept Chem & Environm Sci, Newark, NJ 07102 USA.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.
A synergistic gold-iron (Au-Fe) catalytic system was developed for sequential alkyne hydration and vinyl Au addition to aldehydes or ketones. Fe(acac)(3) was identified as an essential co-catalyst in preventing vinyl Au protodeauration and facilitating nucleophilic additions. Effective C-C bond formation was achieved under mild conditions (room temperature) with excellent regioselectivity and high efficiency (1% [Au], up to 95% yields). The intramolecular reaction was also achieved, giving successful macrocyclization (16-31 ring sizes) with excellent yields (up to 90%, gram scale) without extended dilution (0.2 M), which highlights the great potential of this new crossed aldol strategy in challenging target molecule synthesis.
Welcome to talk about 100-19-6, If you have any questions, you can contact Yuan, T; Ye, XH; Zhao, PY; Teng, S; Yi, YP; Wang, J; Shan, C; Wojtas, L; Jean, J; Chen, H; Shi, X or send Email.. SDS of cas: 100-19-6
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem