Application In Synthesis of 1-(4-Nitrophenyl)ethanone. I found the field of Polymer Science very interesting. Saw the article Design and synthesis of high heat-resistant, soluble, and hydrophobic fluorinated polyimides containing pyridine and trifluoromethylthiophenyl units published in 2019.0, Reprint Addresses Huang, XH; Liu, CJ (corresponding author), Guilin Univ Technol, Key Coll Mat Sci & Engn, Guilin 541004, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.
In this study, a novel diamine monomer, 4-(4-trifluoromethylthiophenyl)-2,6-bis(4-aminophenyl)pyridine (FTPAP) was synthesized through two-step reaction from 4-trifluoromethylthiobenzaldehyde and 4-nitroacetophenone as raw materials, and then the structure of FTPAP was characterized by Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance, and mass spectrometry. A series of fluorinated polyimides were prepared from FTPAP with five commercial dianhydrides, namely, pyromellitic dianhydride, biphenyl tetracarboxylic dianhydride, oxydiphtahalic anhydride, benzophenone tetracarboxylic dianhydride, and 4,4 ‘-(hexafluoroisopropylidene) diphthalic anhydride. The structure and performance of the fluorinated polymers were fully characterized by FTIR, differential scanning calorimetry, thermogravimetric analysis, and wide-angle X-ray diffraction (WAXD). The inherent viscosity of polymers ranged from 0.41 to 1.45 dL g(-1). These polymers displayed good solubility in polar aprotic solvents, such as N,N-dimethylformamide, N,N-dimethylacetamide, dimethyl sulfoxide, and N-methyl-2-pyrrolidone, at room temperature or on heating. Furthermore, they exhibited outstanding thermal stability with glass transition temperatures beyond 305 degrees C, and the temperature of 10% weight loss was in the range of 514-573 degrees C with more than 56% residue at 800 degrees C under nitrogen. Moreover, they showed high optical transparency with the cutoff wavelengths in the range of 385-457 nm and excellent hydrophobic property with contact angle in the range of 82.8-97.6 degrees. In addition, the results of WAXD indicated that all of the polymers presented amorphous structure.
Application In Synthesis of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Huang, XH; Li, H; Liu, CJ; Wei, C or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem