Chidambaram, Ramasamy R.; Sadhasivam, Velu; Mariyappan, Mathappan; Siva, Ayyanar published the article 《Catalytic hydrogenation of aldehydes and ketones using cinchona-bipyridyl-based palladium catalyst》. Keywords: cinchona bipyridyl palladium catalyst preparation surface structure; aldehyde cinchona bipyridyl palladium catalyst hydrogenation; ketone cinchona bipyridyl palladium catalyst hydrogenation; alc preparation.They researched the compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ).SDS of cas: 1762-34-1. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:1762-34-1) here.
Understanding the need for simple, robust and low effluents, in chem. processes, an elegant protocol was developed for the catalytic reduction of aldehydes and ketones to corresponding alcs. which were used in synthetic fragrance applications using cinchona alkaloid-derived palladium catalyst. This system holds good for very low catalyst loading surfaces with the formation of fewer impurities and negligible decomposition under moderate pressure. The conversions and yields ranges from moderate to good (60-80%).
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