Safety of 1-(4-Nitrophenyl)ethanone. Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; CARBONYL-COMPOUNDS; CRYSTAL-STRUCTURES; KETONES; REDUCTION; ALCOHOLS; METAL; ACID; CONSTANTS; ALDEHYDES, Saw an article supported by the Council of Scientific & Industrial Research, New DelhiCouncil of Scientific & Industrial Research (CSIR) – India [01(2841)/16/EMR-II]; IoE Project from the University of Delhi; CSIR, New DelhiCouncil of Scientific & Industrial Research (CSIR) – India; SERB, New DelhiDepartment of Science & Technology (India)Science Engineering Research Board (SERB), India. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Yadav, S; Vijayan, P; Yadav, S; Gupta, R. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
This work presents three mononuclear Ru(ii) complexes of tridentate phosphine-carboxamide based ligands providing a NNP coordination environment. The octahedral Ru(ii) ion shows additional coordination with co-ligands; CO, Cl and CH3OH. All three Ru(ii) complexes were thoroughly characterized including their crystal structures. These Ru(ii) complexes were utilized as catalysts for the transfer hydrogenation of assorted carbonyl compounds, including some challenging biologically relevant substrates, using isopropanol as the hydrogen source. The binding studies illustrated the coordination of the isopropoxide ion by replacing a Ru-ligated chloride ion followed by the generation of the Ru-H intermediate that was isolated and characterized and was found to be involved in the catalysis.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem