Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 70918-54-6, Name is (S)-1,4-Benzodioxane-2-carboxylic acid. In a document type is Article, introducing its new discovery., 70918-54-6
Silver-catalyzed decarboxylative trifluoromethylthiolation of aliphatic carboxylic acids in aqueous emulsion
A silver-catalyzed decarboxylative trifluoromethylthiolation of secondary and tertiary carboxylic acids under mild conditions tolerates a wide range of functional groups. The reaction was dramatically accelerated by its performance in an aqueous emulsion, which was formed by the addition of sodium dodecyl sulfate to water. It was proposed that the radical, which was generated from the silver-catalyzed decarboxylation in the “oil-in-water” droplets, could easily react with the trifluoromethylthiolating reagent to form the product.
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Reference£º
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem