An article Synthesis of new rhodium(III) complex by benzylic C-S bond cleavage of thioether containing NNS donor Schiff base ligand: Investigation of catalytic activity towards transfer hydrogenation of ketones WOS:000598922500005 published article about X-RAY-STRUCTURE; DENSITY-FUNCTIONAL THEORY; IRIDIUM(III) COMPLEXES; EXCITATION-ENERGIES; CARBON-SULFUR; RECENT TOPICS; ELECTROCHEMISTRY; EFFICIENT; ACTIVATION; APPROXIMATION in [Biswas, Sujan; Manna, Chandan Kumar; Naskar, Rahul; Das, Akash; Mondal, Tapan Kumar] Jadavpur Univ, Inorgan Chem Sect, Dept Chem, Kolkata 700032, India in 2021.0, Cited 59.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Computed Properties of C8H7NO3
A new rhodium(III)-triphenylphosphine mixed ligand complex, [Rh(PPh3)(L)Cl-2] (1) is synthesized by benzylic C-S bond cleavage of L-CH2Ph ligand (where, L-CH2Ph = 2-(benzylthio)-N-(pyridin-2-ylmethylene)aniline). The complex is thoroughly characterized by several spectroscopic techniques. Geometry of the complex is confirmed by single crystal X-ray crystallography. Electronic structure, redox properties, absorption and emission properties of the complex were studied. DFT and TDDFT calculations were carried out to interpret the electronic structure and absorption properties of the complex respectively. The synthesized Rh(III) complex was tested as catalyst towards transfer hydrogenation reaction of ketones in iPrOH and an excellent catalytic conversion was observed under mild conditions.
Welcome to talk about 100-19-6, If you have any questions, you can contact Biswas, S; Manna, CK; Naskar, R; Das, A; Mondal, TK or send Email.. Computed Properties of C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem