The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ) is researched.Electric Literature of C12H12N2.Momeni, Badri Z.; Fathi, Nastaran; Abbasi, Reyhaneh; Janczak, Jan published the article 《Exploiting the versatility of pyridyl ligands for the preparation of diorganotin (IV) adducts: spectral, crystallographic and Hirshfeld surface analysis studies》 about this compound( cas:1762-34-1 ) in Applied Organometallic Chemistry. Keywords: diorganotin pyridyl complex preparation Hirshfeld surface analysis; crystal structure mol diorgano tin bidentate pyridyl complex supramol. Let’s learn more about this compound (cas:1762-34-1).
Diorganotin (IV) complexes SnR2X2 (R = Me, Ph; X = Cl, NCS) form a series of versatile complexes when react with bidentate substituted pyridyl ligands. The reaction of dimethyltin dichloride with 5,5′-dimethyl-2,2′-bipyridine (5,5′-Me2bpy) resulted in the formation of [SnMe2Cl2(5,5′-Me2bpy)] (1). Moreover, the reaction of SnMe2(NSC)2 with 4,4′-di-tert-butyl-2,2′-bipyridine (bu2bpy), 1,10-phenanthroline (phen) and 4,7-diphenyl-1,10-phenanthroline (bphen) affords the hexa-coordinated complexes [SnMe2(NCS)2(bu2bpy)] (2), [SnMe2(NCS)2(phen)] (3) and [SnMe2(NCS)2(bphen)] (4), resp. The resulting complexes have been characterized using elemental anal., IR, multinuclear NMR (1H, 13C, 119Sn) and DEPT-135° NMR spectroscopy. On the other hand, the reaction of diphenyltin dichloride with 2,2′-biquinoline (biq) and 4,7-phenantroline (4,7-phen) led to the formation of polymeric complexes of [SnPh2Cl2(4,7-phen)]n (5) and [SnPh2Cl2(biq)]n (6). The NMR spectra, however, reveal the ligand lability in solution and suggest a coordination number of 5. The X-ray crystal structures of complexes [SnMe2Cl2(5,5′-Me2bpy)] (1), [SnMe2(NCS)2(bu2bpy)] (2) and [SnMe2(NCS)2(bphen)] (4) have been determined which reveal that the geometry around the tin atom is distorted octahedral with trans-[SnMe2] configuration. Interestingly, the crystal structure of (H2biq)2[SnPh2Cl4]•2CHCl3 (7) was characterized by X-ray crystallog. from a chloroform solution of [SnPh2Cl2(biq)]n (6) indicating the formation of doubly protonated [H2biq]+ and [Ph2SnCl4]2- which are stabilized by a network of hydrogen bonds with a feature of trans-[SnPh2]. The 3D Hirshfeld surface anal. and 2D fingerprint maps were used for quant. mapping out of the intermol. interactions for 1, 2, 4 and 7 which show the presence of π-π and hydrogen bonding interactions which are associated between donor and acceptor atoms (N, S, Cl) in the solid state.
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