So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Zhou, Meng-Xue; Ren, Ning; Zhang, Jian-Jun; Wang, Da-Qi researched the compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ).SDS of cas: 1762-34-1.They published the article 《Synthesis, crystal structure, thermal, luminescent property and antibacterial activity of lanthanide ternary complexes with p-chlorobenzoic acid and 5,5′-dimethyl-2,2′-bipyridine》 about this compound( cas:1762-34-1 ) in Journal of Molecular Structure. Keywords: rare earth chlorobenzoic acid bipyridine ternary complex preparation structure; antibacterial crystal structure thermal property fluorescence rare earth complex. We’ll tell you more about this compound (cas:1762-34-1).
Four novel lanthanide coordination complexes, [La(p-ClBA)3(5,5′-DM-2,2′-bipy)H2O]n (1), [Ln(p-ClBA)3(5,5′-DM-2,2′-bipy)H2O]2 (Ln = Sm 2, Eu 3, Gd 4) were obtained from the reaction between p-chlorobenzoic acid (p-ClHBA), 5,5′-dimethyl-2,2′-bipyridine (5,5′-DM-2,2′-bipy) and lanthanide nitrate under solvothermal conditions. Single crystal X-ray diffraction anal. showed that complex 1 is a 1D chain structure, crystallized in the monoclinic system, space group P2(1)/n, and formed a 2D sheet through the C-H···O hydrogen bond interactions. While complexes 2-4 were binuclear unit and crystallizes isomorphically in the triclinic system, space group Pi̅. The binuclear unit were assembled into 1D supramol. structures through the O-H···O hydrogen bond interactions along the a-axis and formed a 2D supramol. structures through the π-π stacking interactions along the b-axis. The thermal anal. of four complexes were studied by TG-DSC/FTIR. The solid state photoluminescent properties of complex 3 were investigated at room temperature Moreover, the antibacterial activities of complexes 1-4 on Candida albicans were studied.
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