An article Rh(III)-Catalyzed Direct Amination of Aromatic Ketoximes Enabled by Potassium Acetate WOS:000505254600011 published article about C-H BONDS; INTERMOLECULAR AMIDATION; REGIOSPECIFIC SYNTHESIS; OXIME ETHER; NITROARENES; CYCLIZATION; ARENES; 1H-INDAZOLES; AZOBENZENES; ACTIVATION in [Liu, Lingling; Wang, Ning; Dai, Chenyang; Han, Yi; Yang, Shan; Huang, Zhibin; Zhao, Yingsheng] Soochow Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, 199 Renai St, Suzhou 215123, Jiangsu, Peoples R China in 2019.0, Cited 54.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Recommanded Product: 1-(4-Nitrophenyl)ethanone
A method to achieve rhodium(III)-catalyzed, potassium acetate enabled intermolecular C-H amination of ketoximes using various benzenesulfonamide, especially 4-nitrobenzenesulfonamide is reported. Various aryl ketoximes substituted with electron-withdrawing functional groups were all well tolerated and produced the corresponding products in moderate to good yields. A preliminary mechanistic study revealed that potassium acetate is essential to realizing intermolecular amination.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem