Application In Synthesis of 1-(4-Nitrophenyl)ethanone. In 2019 J CATAL published article about COPPER(II)-CATALYZED AEROBIC OXIDATION; ORGANIC-SOLVENT-FREE; ROOM-TEMPERATURE; DIOXOMOLYBDENUM(VI) COMPLEXES; OXOPEROXO MOLYBDENUM(VI); SULFOXIDATION REACTIONS; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; HYDROGEN-PEROXIDE; MOLECULAR-OXYGEN in [Thiruvengetam, Prabaharan; Chakravarthy, Rajan Deepan; Chand, Dillip Kumar] Indian Inst Technol Madras, Dept Chem, Chennai 600036, Tamil Nadu, India in 2019, Cited 81. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A surfactant based oxodiperoxo molybdenum complex, which could activate molecular oxygen, has been employed as a catalyst for controlled oxidation of benzylic alcohols to corresponding carbonyls. The oxidation reactions were carried out under aqueous environment, however, in the absence of any extraneous base or co-catalyst. Sensitive/oxidizable functional groups like cyano, sulfide, hydroxyl, aryl-hydroxyl, alkene (internal/terminal), alkyne (internal/terminal), and acetal were tolerated during the transformations. Such selectivity is attributed to the mild nature of the catalyst. The methodology could also be scaled-up for multi-gram synthesis and the protocol is likely to find practical use since it requires an inexpensive recyclable-catalyst and easily available oxidant (under green conditions). A plausible mechanism is proposed with the help of preliminary computational study. (C) 2019 Elsevier Inc. All rights reserved.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem