In 2020.0 ORG BIOMOL CHEM published article about MANGANESE-DIOXIDE OXIDATION; HIGHER ALPHA-OLEFINS; METHYL KETONES; REGIOSELECTIVE OXIDATION; ASYMMETRIC ALLYLATION; AROMATIC-COMPOUNDS; SYSTEM; CONVENIENT; PRINCIPLES; DISCOVERY in [Fernandes, Rodney A.; Ramakrishna, Gujjula, V; Bethi, Venkati] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India in 2020.0, Cited 80.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. SDS of cas: 100-19-6
Efficient and mild reaction conditions for Wacker-type oxidation of terminal olefins of less explored homoallyl alcohols to beta-hydroxy-methyl ketones have been developed by using a Pd(ii) catalyst and MnO(2)as a co-oxidant. The method involves mild reaction conditions and shows good functional group compatibility along with high regio- and chemoselectivity. While our earlier system of PdCl2/CrO3/HCl produced alpha,beta-unsaturated ketones from homoallyl alcohols, the present method provided orthogonally the beta-hydroxy-methyl ketones. No overoxidation or elimination of benzylic and/or beta-hydroxy groups was observed. The method could be extended to the oxidation of simple terminal olefins as well, to methyl ketones, displaying its versatility. An application to the regioselective synthesis of gingerol is demonstrated.
SDS of cas: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Fernandes, RA; Ramakrishna, GV; Bethi, V or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem