Decrypt The Mystery Of 2160535-56-6

Compounds in my other articles are similar to this one((R)-N-((R)-(5-(Diphenylphosphanyl)-9,9-dimethyl-9H-xanthen-4-yl)(4-methoxyphenyl)methyl)-2-methylpropane-2-sulfinamide)Category: benzodioxans, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 2160535-56-6, is researched, SMILESS is CC([S@](N[C@@H](C1=CC=CC(C2(C)C)=C1OC3=C2C=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=C(OC)C=C6)=O)(C)C, Molecular C39H40NO3PSJournal, Article, Research Support, Non-U.S. Gov’t, Angewandte Chemie, International Edition called Gold-Catalyzed Asymmetric Intramolecular Cyclization of N-Allenamides for the Synthesis of Chiral Tetrahydrocarbolines, Author is Wang, Yidong; Zhang, Peichao; Di, Xiaoyu; Dai, Qiang; Zhang, Zhan-Ming; Zhang, Junliang, the main research direction is gold catalyzed asym intramol cyclization allenamide chiral hydrocarboline synthesis; chiral sulfinamide phosphine ligand gold catalyzed asym intramol cyclization; desbromoarborescidine A synthesis desbromoarborescidine C formal synthesis; deplancheine formal synthesis; desymmetrization allenamide; allenamides; cyclization; enantioselectivity; gold; tetrahydrocarboline.Category: benzodioxans.

Highly enantioselective gold-catalyzed intramol. cyclization of N-allenamides was implemented by utilizing a designed chiral sulfinamide phosphine ligand (PC-Phos) [e.g., allenamide I → tetrahydrocarboline II (99%, 96% ee) in presence of Me2S.AuCl, AgNTf2 and ligand III in CH2Cl2 at -50°]. This represents the first example of highly enantioselective intramol. cyclization of N-allenamides. The practicality of this reaction was validated in the total synthesis of (R)-desbromoarborescidine A and formal synthesis of (R)-desbromoarborescidine C and (R)-deplancheine. Moreover, the catalyst system PC-Phos/AuNTf2 proved to be specifically efficient to promote the desymmetrization of N-allenamides in excellent yields with satisfactory ee values.

Compounds in my other articles are similar to this one((R)-N-((R)-(5-(Diphenylphosphanyl)-9,9-dimethyl-9H-xanthen-4-yl)(4-methoxyphenyl)methyl)-2-methylpropane-2-sulfinamide)Category: benzodioxans, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Fun Route: New Discovery of 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)SDS of cas: 1762-34-1, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

SDS of cas: 1762-34-1. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about A new mononuclear nickel complex with 5,5′-dimethyl-2,2′-bipyridine: Synthesis, structural investigation and catalytic properties.

The new [Ni(dmbpy)(H2O)4]SeO4 (1) complex (dmbpy = 5,5′-dimethyl-2,2′-bipyridine or C12H12N2), based on mononuclear nickel(II) and bi-at. bridging ligands was successfully synthesized by hydrothermal method. The crystals were characterized by x-ray single-crystal diffraction, crystallizing in the monoclinic system, space group P21/c. Their crystal structure consists of metallic cations octahedrally coordinated by four water mols. and two nitrogen atoms coming from the organic mol. [NiN2O4], and a selenate anion (SeO4)2-. Their crystal packing is ensured by a three-dimensional network of O-H. O hydrogen bonds between the cation and anion moieties, and π… π interactions between the pyridine rings of the organic moieties of the same layer. The thermal anal. discloses dehydration between 148° and 210°, leading to an anhydrous compound [Ni(dmbpy)]SeO4. The study of vibrational absorption and Raman scattering spectra allows bringing addnl. information to those obtained by x-ray diffraction. The optical band gap was calculated from the UV-visible absorbance spectra using classical Tauc relation which is 3.58 eV. The catalytic evaluation of [Ni(dmbpy)(H2O)4]SeO4 on Heck and Sonogashira coupling reactions, activated by ultrasonic irradiation, results in encouraging yields for a very short times with a remarkable selectivity of the form (E) with respect to (Z) during the arylation of styrene, making this complex a promising catalyst for both types of reactions. The coupling products of the Heck and Sonogashira coupling reaction ((Z)-/(E)- Stilbene and Diphenylacetylene, resp.) were examined by 13C NMR and 1H NMR. These spectroscopic measurements provide extremely valuable information on the structure of the mols. obtained.

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)SDS of cas: 1762-34-1, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Fun Route: New Discovery of 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Category: benzodioxans, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 1762-34-1, is researched, Molecular C12H12N2, about CO2 to CO: Photo- and Electrocatalytic Conversion Based on Re(I) Bis-Arene Frameworks: Synergisms Between Catalytic Subunits, the main research direction is ruthenium complex electrochem carbon dioxide reduction.Category: benzodioxans.

Reduction of CO2 to CO and H2O is a two electron/two proton process. For this process, multinuclear complexes offer advantages by concentrating reduction equivalent more efficiently than mononuclear systems. We present novel complexes with [Re(η6-C6H6)2]+ as scaffold conjugated to one or two catalytically active [Ru(dmbpy)(CO)2Cl2] subunits (dmbpy=5,5′-dimethyl-2,2′-bipyridine). The [Re(η6-C6H6)2]+ scaffold was chosen due to its very high photo- and chem. stability, as well as the multiple degrees of freedom it offers for any conjugated functionalities. High efficiency and selectivity for the reduction of CO2 to CO (over H2 or HCOOH) is reported. TONs and TOFs were found to be comparable or higher than for the catalyst subunit without the rhenium framework. Cooperativity in photo- and electrocatalysis is observed for the complex comprising two catalytic subunits. The synergistic communication between the two catalytic subunits is responsible for the observed enhancement in both photo- and electrocatalytic performance. Confirmation of electronic communication between the two [Ru(dmbpy)(CO)2Cl2] subunits as well as the elucidation of a possible mechanism was supported by electrochem., IR-spectroelectrochem. and DFT studies.

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Category: benzodioxans, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Awesome and Easy Science Experiments about 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Safety of 5,5′-Dimethyl-2,2′-bipyridine, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 5,5′-Dimethyl-2,2′-bipyridine(SMILESS: CC1=CN=C(C=C1)C1=NC=C(C)C=C1,cas:1762-34-1) is researched.Category: chiral-catalyst. The article 《Boosting Photocatalytic Activities for Organic Transformations through Merging Photocatalyst and Transition-Metal Catalyst in Flexible Polymers》 in relation to this compound, is published in ACS Catalysis. Let’s take a look at the latest research on this compound (cas:1762-34-1).

The merger of photocatalysis and transition-metal catalysis is of particular interest to develop useful and challenging synthetic methodologies. The catalytic activities of conventional dual-catalytic systems, however, are limited by the low synergistic efficiency between discrete catalytic centers due to their long average distance in solution Herein we carefully decorated Ir(III) photosensitizers and Ni(II) transition-metal catalyst into flexible polymers to afford two polymer-supported dual catalysts (P1-Ni and P2-Ni). These polyelectrolyte-type metallopolymers assembled into spherical polymer particles in some polar solvents. Their unique mol. and assembled structure contributed to shortening the distance between catalytic centers and increasing the local catalysts′ concentration within the catalyst, thereby greatly facilitating their electron, energy, and organic radical transfers during the catalytic cycles. The enhanced energy interaction and matched redox potential between two catalytic centers within the polymer were confirmed by steady- and transient-state luminescent spectra and cyclic voltammetry. These features enable them in catalyzing challenging organic transformations that involve efficiently incorporated photocatalytic and transition-metal catalytic cycles. We demonstrated that these two catalysts were highly effective in catalyzing C-S cross-coupling, C-O functionalized, C-N cross-coupling, and C-C cross-coupling reactions with broad substrate scopes and low catalyst loadings with turnover numbers of ~3100, ~1500, ~1400, and ~500, resp. This work provides a general methodol. to merge photosensitizer and transition-metal catalyst in a flexible polymer for significantly boosting the catalytic activity.

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Safety of 5,5′-Dimethyl-2,2′-bipyridine, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Share an extended knowledge of a compound : 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Computed Properties of C12H12N2, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Computed Properties of C12H12N2. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Nickel-Catalyzed Cross-Coupling of Ethyl Chlorofluoroacetate with Aryl Bromides. Author is Li, Han; Sheng, Jie; Wu, Bing-Bing; Li, Yan; Wang, Xi-Sheng.

A combinatorial nickel-catalyzed monofluoroalkylation of aryl bromides with the industrial raw regent Et chlorofluoroacetate has been developed. The two key factors to successful conversion are the combination of nickel with readily available nitrogen and phosphine ligands and the using of a mixture of different solvents. Mechanistic investigations indicated a new zinc regent might generated in situ and be involved in the reaction process.

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Computed Properties of C12H12N2, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Never Underestimate the Influence Of 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Reference of 5,5′-Dimethyl-2,2′-bipyridine, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Stereoselective self-assembly of DNA binding helicates directed by the viral β-annulus trimeric peptide motif.Reference of 5,5′-Dimethyl-2,2′-bipyridine.

Combining coordination chem. and peptide engineering offers extraordinary opportunities for developing novel mol. (supra)structures. Here, we demonstrate that the β-annulus motif is capable of directing the stereoselective assembly of designed peptides containing 2,2′-bipyridine ligands into parallel three-stranded chiral peptide helicates, and that these helicates selectively bind with high affinity to three-way DNA junctions.

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Reference of 5,5′-Dimethyl-2,2′-bipyridine, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Some scientific research about 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)HPLC of Formula: 1762-34-1, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

HPLC of Formula: 1762-34-1. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Water-stable Zn-based metal-organic framework with hydrophilic-hydrophobic surface for selective adsorption and sensitive detection of oxo-anions and pesticides in aqueous medium. Author is Kaur, Harpreet; Walia, Sidharth; Karmakar, Anirban; Krishnan, Venkata; Koner, Rik Rani.

Given the importance of surface-functionalized materials with improved adsorption and detection properties for targeted applications, we report herein the design and development of a water-stable luminescent Zn-based metal-organic framework (Zn-MOF) with the hydrophobic-hydrophilic surface property. The developed luminescent Zn(II)-MOF {[Zn(PA2-)(dmbpy)](DMF)}n was synthesized via a solvothermal method using pamoic acid (PA) and 5,5′-dimethyl-2,2′-bipyridine (dmbpy) with free functional groups (hydroxyl and Me groups). Careful single-crystal structure anal. revealed a 3-dimensional hydrogen-bonded network with a one-dimensional channel and functionalized surface. The surface functionalization was achieved through rational choice of ligands bearing Me and hydroxyl groups as suitable hydrophobic and hydrophilic functionalities resp., leading to a stable MOF in the aqueous medium. The MOF was used as an adsorbent for selective adsorption of monovalent permanganate anion (MnO4-) over other polyvalent oxo-anions as well as an optical platform for the detection of oxo-anions (permanganate (MnO-4), dichromate (Cr2O72-) and chromate (CrO42-)) and pesticide (2,6-dichloro-4-nitroaniline (2,6-DCNA)) in the aqueous medium. Overall, a combination of luminescent nature and hydrophilic-hydrophobic surface property makes the developed Zn-MOF an interesting platform for environmental application.

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)HPLC of Formula: 1762-34-1, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Chemical Research in 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Synthetic Route of C12H12N2, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ) is researched.Synthetic Route of C12H12N2.Gomez-Gonzalez, Jacobo; Bouzada, David; Perez-Marquez, Lidia A.; Sciortino, Giuseppe; Marechal, Jean-Didier; Vazquez Lopez, Miguel; Vazquez, M. Eugenio published the article 《Stereoselective self-assembly of DNA binding helicates directed by the viral β-annulus trimeric peptide motif》 about this compound( cas:1762-34-1 ) in Bioconjugate Chemistry. Keywords: peptide solid phase synthesis bipyridine self assembly chiral helicate; chiral peptide helicate complexation iron DNA binding; bipyridine peptide supramol structure MD simulation fluorescence; iron complex peptide stability. Let’s learn more about this compound (cas:1762-34-1).

Combining coordination chem. and peptide engineering offers extraordinary opportunities for developing novel mol. (supra)structures. Here, we demonstrate that the β-annulus motif is capable of directing the stereoselective assembly of designed peptides containing 2,2′-bipyridine ligands into parallel three-stranded chiral peptide helicates, and that these helicates selectively bind with high affinity to three-way DNA junctions.

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Synthetic Route of C12H12N2, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Extracurricular laboratory: Synthetic route of 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Application In Synthesis of 5,5′-Dimethyl-2,2′-bipyridine, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Application In Synthesis of 5,5′-Dimethyl-2,2′-bipyridine. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about [Ni(5,5′-dmbpy)3]2Ag4.9I8.9·4H2O: A discrete iodoargentate with transition metal complexes. Author is Zhang, Bo; Li, Wei-An; Li, Jun; Xu, Yu-Ping; Xu, Ya-Ru; Wang, Wen-Hao; Zou, Guo-Dong.

Using the transition metal complex as templating agent, a new discrete iodoargentate compound, [Ni(5,5′-dmbpy)3]2Ag4.9I8.9·4H2O (5,5′-dmbpy = 5,5′-dimethyl-2,2′-bipyridine) (1) was solvothermally prepared and structurally characterized. Compound 1 has a discrete anionic moiety of [Ag4.9I8.9]4- constructed by three types of fundamental building units, i.e., [AgI2] dumbbell, [AgI3] triangle and [AgI4] tetrahedron. It possesses a band gap of 2.07 eV, and exhibits fascinating photoelec. property with the photocurrent value of around 0.5μA/cm2. Its thermal stability and Hirshfeld surface analyses were also investigated.

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Application In Synthesis of 5,5′-Dimethyl-2,2′-bipyridine, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Fun Route: New Discovery of 1762-34-1

Compounds in my other articles are similar to this one(5,5′-Dimethyl-2,2′-bipyridine)Application of 1762-34-1, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Taylor, James O.; Veenstra, Florentine L. P.; Chippindale, Ann M.; Calhorda, Maria Jose; Hartl, Frantisek published the article 《Group 6 Metal Complexes as Electrocatalysts of CO2 Reduction: Strong Substituent Control of the Reduction Path of [Mo(η3-allyl)(CO)2(x,x’-dimethyl-2,2′-bipyridine)(NCS)] (x = 4-6)》. Keywords: methylbipyridine allyl molybdenum carbonyl complex preparation redox potential DFT; crystal structure methylbipyridine allyl molybdenum carbonyl complex; mol structure methylbipyridine allyl molybdenum carbonyl complex; optimized geometry bipyridine allylmolybdenum complex anion radical complex DFT.They researched the compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ).Application of 1762-34-1. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:1762-34-1) here.

[Mo(η3-allyl)(CO)2(x,x’-dmbipy)(NCS)] (dmbipy = dimethyl-2,2′-bipyridine; x = 4-6) were synthesized and their electrochem. reduction studied using combined cyclic voltammetry (CV) and variable-temperature spectroelectrochem. (IR/UV-visible SEC) in THF and butyronitrile (PrCN), at Au and Pt electrodes. The exptl. results, strongly supported by d. functional theory (DFT) calculations, indicate that the general cathodic path of these Group 6 organometallic complexes is closely related to that of the intensively studied class of Mn tricarbonyl α-diimine complexes, which, themselves, have recently been identified as important smart materials for catalytic CO2 reduction The di-Me substitution on the 2,2′-bipyridine ligand backbone has presented new insights into this emerging class of catalysts. For the 1st time, the 2e- reduced 5-coordinate anions [Mo(η3-allyl)(CO)2(x,x’-dmbipy)]- were directly observed with IR spectroelectrochem. (IR SEC). The role of steric and electronic effects in determining the reduction-induced reactivity was also studied. For the 6,6′-dmbipy, the primary 1e- reduced radical anions exert unusual stability, radically changing the follow-up cathodic path. The 5-coordinate anion [Mo(η3-allyl)(CO)2(6,6′-dmbipy)]- remains stable at low temperature in strongly coordinating butyronitrile and does not undergo dimerization at elevated temperature, in sharp contrast to reactive [Mo(η3-allyl)(CO)2(4,4′-dmbipy)]- that tends to dimerize in a reaction with the parent complex. The complex with the 5,5′-dmbipy ligand combines both types of reactivity. Under aprotic conditions, the different properties of [Mo(η3-allyl)(CO)2(x,x’-dmbipy)]- are also reflected in their reactivity toward CO2. Preliminary CV and IR SEC results reveal differences in the strength of CO2 coordination at the free axial position. Catalytic waves attributed to the generation of the 5-coordinate anions were observed using CV, but only a modest catalytic performance toward the production of formate was demonstrated by IR SEC. For 6,6′-dmbipy, a stronger catalytic effect was observed for the Au cathode, compared to Pt.

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Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem