Category: 1762-34-1

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Nickel-Catalyzed Cross-Electrophile C(sp3)-Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes, the main research direction is nickel catalyst cross coupling alkyl bromide vinyl chloro silane; alkyl silane organosilane preparation.Category: benzodioxans.

Cross-electrophile C-Si coupling has emerged as a promising tool for the construction of organosilanes, but the potential of this method remains largely unexplored. Herein, we report a C(sp3)-Si coupling of unactivated alkyl bromides with vinyl chlorosilanes. The reaction proceeds under mild conditions, and it offers a new approach to alkylsilanes. Functionalities such as Grignard-sensitive groups (e.g., acid, amide, alc., ketone, and ester), acid-sensitive groups (e.g., ketal and THP protection), alkyl fluoride and chloride, aryl bromide, alkyl tosylate and mesylate, silyl ether, and amine were tolerated. Incorporation of the -Si(vinyl)R2 moiety into complex mols. and the immobilization of a glass surface by formed organosilanes were demonstrated.

Here is just a brief introduction to this compound(1762-34-1)Category: benzodioxans, more information about the compound(5,5′-Dimethyl-2,2′-bipyridine) is in the article, you can click the link below.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Physical Chemistry Chemical Physics called H/D solvent isotope effects on the photoracemization reaction of enantiomeric the tris(2,2′-bipyridine)ruthenium(II) complex and its analogues, Author is Asahara, Masahiro; Kurimoto, Haruhiko; Nakamizu, Masato; Hattori, Shingo; Shinozaki, Kazuteru, which mentions a compound: 1762-34-1, SMILESS is CC1=CN=C(C=C1)C1=NC=C(C)C=C1, Molecular C12H12N2, Related Products of 1762-34-1.

This work assessed solvent isotope effects on the photoracemization rate and emission lifetime for [Ru(bpy)3]2+ (bpy = 2,2′-bipyridine) in water. An anal. of the effects of temperature on photoracemization rate and emission lifetime demonstrated that the transition from one enantiomer to the other is unaffected by the isotopic composition of the solvent. Also deactivation from the metal-to-ligand charge-transfer (3MLCT) excited state to the ground state is responsible for the solvent isotope effect on the photoracemization rate. The photoracemization reaction proceeds via a bond-breaking mechanism. In this process, a five-coordinated species produced through breaking of the Ru-N bond in the 3d-d* state undergoes a structural change to produce an achiral five-coordinated species. An anal. of the effect of temperature on emission lifetime, excluding the activation to the 3d-d* state that leads to the structural change, showed that the solvent isotopic composition affects deactivation from the 4th MLCT state.

Here is just a brief introduction to this compound(1762-34-1)Related Products of 1762-34-1, more information about the compound(5,5′-Dimethyl-2,2′-bipyridine) is in the article, you can click the link below.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ) is researched.Name: 5,5′-Dimethyl-2,2′-bipyridine.Kaur, Harpreet; Walia, Sidharth; Karmakar, Anirban; Krishnan, Venkata; Koner, Rik Rani published the article 《Water-stable Zn-based metal-organic framework with hydrophilic-hydrophobic surface for selective adsorption and sensitive detection of oxo-anions and pesticides in aqueous medium》 about this compound( cas:1762-34-1 ) in Journal of Environmental Chemical Engineering. Keywords: zinc metal organic framework hydrophilic hydrophobic oxoanion pesticide detection. Let’s learn more about this compound (cas:1762-34-1).

Given the importance of surface-functionalized materials with improved adsorption and detection properties for targeted applications, we report herein the design and development of a water-stable luminescent Zn-based metal-organic framework (Zn-MOF) with the hydrophobic-hydrophilic surface property. The developed luminescent Zn(II)-MOF {[Zn(PA2-)(dmbpy)](DMF)}n was synthesized via a solvothermal method using pamoic acid (PA) and 5,5′-dimethyl-2,2′-bipyridine (dmbpy) with free functional groups (hydroxyl and Me groups). Careful single-crystal structure anal. revealed a 3-dimensional hydrogen-bonded network with a one-dimensional channel and functionalized surface. The surface functionalization was achieved through rational choice of ligands bearing Me and hydroxyl groups as suitable hydrophobic and hydrophilic functionalities resp., leading to a stable MOF in the aqueous medium. The MOF was used as an adsorbent for selective adsorption of monovalent permanganate anion (MnO4-) over other polyvalent oxo-anions as well as an optical platform for the detection of oxo-anions (permanganate (MnO-4), dichromate (Cr2O72-) and chromate (CrO42-)) and pesticide (2,6-dichloro-4-nitroaniline (2,6-DCNA)) in the aqueous medium. Overall, a combination of luminescent nature and hydrophilic-hydrophobic surface property makes the developed Zn-MOF an interesting platform for environmental application.

I hope my short article helps more people learn about this compound(5,5′-Dimethyl-2,2′-bipyridine)Name: 5,5′-Dimethyl-2,2′-bipyridine. Apart from the compound(1762-34-1), you can read my other articles to know other related compounds.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Asahara, Masahiro; Kurimoto, Haruhiko; Nakamizu, Masato; Hattori, Shingo; Shinozaki, Kazuteru published the article 《H/D solvent isotope effects on the photoracemization reaction of enantiomeric the tris(2,2′-bipyridine)ruthenium(II) complex and its analogues》. Keywords: preparation ruthenium bipyridine phenanthroline complex; solvent isotope effect ruthenium bipyridine phenanthroline complex; photoracemization reaction ruthenium bipyridine phenanthroline complex.They researched the compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ).Computed Properties of C12H12N2. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:1762-34-1) here.

This work assessed solvent isotope effects on the photoracemization rate and emission lifetime for [Ru(bpy)3]2+ (bpy = 2,2′-bipyridine) in water. An anal. of the effects of temperature on photoracemization rate and emission lifetime demonstrated that the transition from one enantiomer to the other is unaffected by the isotopic composition of the solvent. Also deactivation from the metal-to-ligand charge-transfer (3MLCT) excited state to the ground state is responsible for the solvent isotope effect on the photoracemization rate. The photoracemization reaction proceeds via a bond-breaking mechanism. In this process, a five-coordinated species produced through breaking of the Ru-N bond in the 3d-d* state undergoes a structural change to produce an achiral five-coordinated species. An anal. of the effect of temperature on emission lifetime, excluding the activation to the 3d-d* state that leads to the structural change, showed that the solvent isotopic composition affects deactivation from the 4th MLCT state.

I hope my short article helps more people learn about this compound(5,5′-Dimethyl-2,2′-bipyridine)Computed Properties of C12H12N2. Apart from the compound(1762-34-1), you can read my other articles to know other related compounds.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

COA of Formula: C12H12N2. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Cross-Electrophile C(sp2)-Si Coupling of Vinyl Chlorosilanes. Author is Duan, Jicheng; Wang, Ke; Xu, Guang-Li; Kang, Shaolin; Qi, Liangliang; Liu, Xue-Yuan; Shu, Xing-Zhong.

The cross-electrophile coupling has become a powerful tool for C-C bond formation, but its potential for forging the C-Si bond remains unexplored. Here we report a cross-electrophile Csp2-Si coupling reaction of vinyl/aryl electrophiles with vinyl chlorosilanes. This new protocol offers an approach for facile and precise synthesis of organosilanes with high mol. diversity and complexity from readily available materials. The reaction proceeds under mild and non-basic conditions, demonstrating a high step economy, broad substrate scope, wide functionality tolerance, and easy scalability. The synthetic utility of the method is shown by its efficient accessing of silicon bioisosteres, the design of new BCB-monomers, and studies on the Hiyama cross-coupling of vinylsilane products.

I hope my short article helps more people learn about this compound(5,5′-Dimethyl-2,2′-bipyridine)COA of Formula: C12H12N2. Apart from the compound(1762-34-1), you can read my other articles to know other related compounds.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Zhu, Yao; He, Yong-Qin; Tian, Wan-Fa; Wang, Mei; Zhou, Zhao-Zhao; Song, Xian-Rong; Ding, Hai-Xin; Xiao, Qiang published an article about the compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1,SMILESS:CC1=CN=C(C=C1)C1=NC=C(C)C=C1 ).Synthetic Route of C12H12N2. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:1762-34-1) through the article.

A hydroxyl-assisted, organophotoredox/cobalt dual catalyzed annulation of 2-propynolphenols I [R1 = H, R2 = H, F, Cl, Br, MeO2C, Me; R1 = Cl, R2 = H; R1 = R2 = F; R3 = R4 = Me, Ph, 4-FC6H4, 3-F3CC6H4, etc.; R3 = Ph, R4 = Me, 4-ClC6H4, 2-FC6H4, 4-F3CC6H4, 2-thienyl, etc.; R3 = 4-FC6H4, R4 = 4-MeOC6H4; R3R4 = (CH2)5] to form 2-(hydroxymethyl)benzo[b]furans II has been developed by employing 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) as photosensitizer and CoCl2(PPh3)2/5,5′-dimethyl-2,2′-bipyridine as cobalt catalytic precursor. Various substrates and functional groups were tolerated. The practical applications of this reaction were further demonstrated by enlarged gram-scale and various derivations for complex heterocycles. Primary mechanistic studies suggested the involvement of cobalt-hydride mediated hydrogen atom transfer (HAT) process.

I hope my short article helps more people learn about this compound(5,5′-Dimethyl-2,2′-bipyridine)Synthetic Route of C12H12N2. Apart from the compound(1762-34-1), you can read my other articles to know other related compounds.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 1762-34-1, is researched, Molecular C12H12N2, about Regulating the magnetic dynamics of mononuclear β-diketone Dy(III) single-molecule magnets through the substitution effect on capping N-donor coligands, the main research direction is trifluoronaphthylbutanedione mononuclear beta diketone dysprosium nitrogen donor complex; single mol magnet substitution effect trifluoronaphthylbutanedione dysprosium nitrogen donor.Synthetic Route of C12H12N2.

A series of five mononuclear β-diketonate-Dy(III) complexes, with formulas Dy(ntfa)3(Br-bpy) (1), Dy(ntfa)3(Br2-bpy) (2), Dy(ntfa)3(5,5-(CH3)2-bpy) (3), Dy(ntfa)3(4,4-((CH3)3)2-bpy) (4) and Dy(ntfa)3(4,4-(CH3)2-bpy) (5) (ntfa = 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione, Br-bpy = 5-bromo-2,2′-bipyridine, Br2-bpy = 4,4′-dibromo-2,2′-bipyridine, 5,5-(CH3)2-bpy = 5,5′-di-methyl-2,2′-bipyridine, 4,4-((CH3)3)2-bpy = 4,4′-di-tert-butyl-2,2′-bipyridine, and 4,4-(CH3)2-bpy = 4,4′-di-methyl-2,2′-bipyridine), have been prepared by altering the capping N-donor coligands. Dy(III) ions in all complexes possess N2O6 octa-coordinated environments, displaying a distorted square antiprismatic D4d symmetry in complexes 1-4, as well as a triangular dodecahedron D2d symmetry in 5. Magnetic investigations evidence the SIM behavior in the five complexes with the energy barriers (Ueff) of 104.19 K (1), 122.93 K (2), 84.20 K (3), 64.16 K (4) and 80.23 K (5) under zero applied dc field. The potential QTM effects in the title complexes are successfully suppressed in the presence of the extra applied fields. The crystal field parameters and orientations of the magnetic easy axes were obtained from the simulation of the magnetic data and the electrostatic model calculation The distinct electronic effects originating from the subtle changes of the substituents on the capping N-donor coligands induce varying coordination microenvironments and geometries on the Dy(III) sites, further drastically impacting the overall magnetic properties of the title complexes. The disparities of the uniaxial anisotropy and the magnetic dynamics for 1-5 have been elucidated by ab initio calculations as well.

I hope my short article helps more people learn about this compound(5,5′-Dimethyl-2,2′-bipyridine)Synthetic Route of C12H12N2. Apart from the compound(1762-34-1), you can read my other articles to know other related compounds.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

SDS of cas: 1762-34-1. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Two nonporous MOFs with uncoordinated carboxylate groups: Fillers for enhancing the proton conductivities of nafion membrane. Author is Li, Rong-Yun; Liu, Hou-Ting; Chu, Zhi-Tong; Zhou, Chuan-Cong; Lu, Jing; Wang, Su-Na.

Two nonporous MOFs [Ni(L)0.5 (Mbpy)(H2O)2]2 (1) and [Cd(H2L)(Mbpy)]n (2) (H4L = 5,5′-(butane-1,4-diylbis (oxy))diisophthalic acid, Mbpy = 5,5′-dimethyl-2,2′-bipyridine) were obtained through hydrothermal reactions under different pH values reaction condition. Structure analyses reveal that there are uncoordinated deprotonated and protonated carboxylate groups in compounds 1 and 2, resp., which are confirmed by IR spectra. The XRD and TG studies indicate that both of compounds exhibit good water and thermal stability. The proton conductivities of the Nafion membrane doped by compounds 1 and 2 were studied. Compound 2 can enhance the proton conductivity of the composite membrane ∼29% higher than that of pure Nafion. The water uptakes of 1/Nafion and 2/Nafion composite membrane are similar and slightly higher than that of pure Nafion membrane. The apparently high proton conductivity of 2/Nafion membrane should be attributed to the high proton d. of 2 framework, which is resulted by the protonated uncoordinated carboxylate acid groups.

I hope my short article helps more people learn about this compound(5,5′-Dimethyl-2,2′-bipyridine)SDS of cas: 1762-34-1. Apart from the compound(1762-34-1), you can read my other articles to know other related compounds.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Applied Organometallic Chemistry called Synthesis, structures, thermal behaviour, luminescence and magnetic properties of lanthanide complexes constructed from 2,6-dimethylbenzoic acid and 5,5′-dimethyl-2,2′-bipyridine, Author is Li, Ying-Ying; Ren, Ning; He, Shu-Mei; Wang, Shu-Ping; Zhang, Jian-Jun, which mentions a compound: 1762-34-1, SMILESS is CC1=CN=C(C=C1)C1=NC=C(C)C=C1, Molecular C12H12N2, Synthetic Route of C12H12N2.

Six new lanthanide complexes, with the formula [La(2,6-DMBA)3(5,5′-DM-2,2′-bipy)(H2O)]2 (1) and [Ln(2,6-DMBA)3(5,5′-DM-2,2′-bipy)]2 (Ln = Tb(2), Dy(3), Ho(4), Pr(5), Nd(6)) (2,6-DMBA = 2,6-dimethylbenzoate, 5,5′-DM-2,2′-bipy = 5,5′-dimethyl-2,2′-bipyridine) have been successfully synthesized and characterized. These title complexes have three different structural types. The structure of complex 1(type I) contains coordination water mols., and the coordination number is 8. The coordination numbers of complexes 2-4 and 5-6 are 8 and 9, showing a distorted square antiprism geometry and distorted monocapped square anti-prismatic geometry, resp. However they have the same general formula and they can be all assembled into the same 1D, 2D supramol. structures via the C-H···O hydrogen bonding interactions, which is interesting in previous lanthanide complexes. The complexes were analyzed by TG-DSC/FTIR. In addition, the visible light luminescence experiments of Tb (III) complex was carried out, and the characteristic luminescence behavior of strong green color was shown. And the fluorescence lifetime and intrinsic quantum yield were calculated The magnetic properties of complexes 2-4 were also studied, and the results showed that complex 3 and complexes 2, 4 have ferromagnetic interactions and antiferromagnetic interactions, resp.

Here is just a brief introduction to this compound(1762-34-1)Synthetic Route of C12H12N2, more information about the compound(5,5′-Dimethyl-2,2′-bipyridine) is in the article, you can click the link below.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem

HPLC of Formula: 1762-34-1. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Structure analysis and biological functionalities of a nickel(II) complex and its sonochemically synthesized nano form: in vitro anti-proliferation, DNA binding, antibacterial and molecular docking study. Author is Kondori, Tahere; Akbarzadeh-T, Niloufar; Ghaznavi, Habib; Karimi, Zeinab; Sheervalilou, Roghayeh; Dusek, Michal; Eigner, Vaclav; Shahraki, Omolbanin.

A compound of {[Ni(5,5′-Dimethyl-2,2′-bipyridine)3](SCN)2}2(a) was synthesized and characterized by FTIR, UV-visible spectroscopy, elemental anal., luminescence and x-ray crystallog. The single crystals were obtained by slow crystallization from a methanol solution The complex is composed of nickel cation chelated by three neutral bipyridine ligands and two (SCN-) ions outside the coordination sphere. The nano form of the synthesized complex (b) was prepared by a sonochem. process and confirmed with XRD, SEM and FTIR. The average size of the particles was 37 nm from SEM. Thermodn. parameters (ΔH°, ΔS° and ΔG°) calculated from FS-DNA interaction of complexes showed that hydrogen bonding and van der Waals interactions have an essential function in the interaction of DNA-Ni(II) complex, and the interaction mode is groove binding. Viscosity measurement illustrated that relative viscosity of DNA remained unchanged with the adding concentrations of complexes. CD spectra showed that the structure of DNA was changed. The antibacterial properties were investigated in vitro against standard Gram-pos. and Gram-neg. bacterial strains. The results of antibacterial tests showed that (a) was a stronger antibacterial agent than the free ligand, and that the antibacterial effect of (b) was stronger than the one of (a). The cytotoxicity activity experiments against MCF-7, KB and A549 cells revealed low to moderate antiproliferative activity of the complex (b) against cancer cells. The mol. docking results exhibited groove mode of binding, confirming previously obtained data from spectroscopy, viscometry and CD.

Here is just a brief introduction to this compound(1762-34-1)HPLC of Formula: 1762-34-1, more information about the compound(5,5′-Dimethyl-2,2′-bipyridine) is in the article, you can click the link below.

Reference:
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem