A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, 70918-54-6, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 70918-54-6, Name is (S)-1,4-Benzodioxane-2-carboxylic acid, molecular formula is C9H8O4. In a Article, authors is Ramirez, Nieves P.£¬once mentioned of 70918-54-6
Decarboxylative Giese-Type Reaction of Carboxylic Acids Promoted by Visible Light: A Sustainable and Photoredox-Neutral Protocol
We describe herein a transition-metal-free method for the decarboxylative generation of radicals from carboxylic acids and their 1,4-addition to Michael acceptors. The Fukuzumi catalyst (9-mesitylene-10-methylacridinium perchlorate, [Acr-Mes]ClO4) enabled this transformation under visible-light irradiation at room temperature with CO2 as the only byproduct. The scope and limitations of this protocol were examined by using a range of Michael acceptors (15 examples) and carboxylic acids (18 examples). The use of 3-hydroxypivalic acid in this protocol allowed the straightforward formation of a diastereomerically pure delta-lactone. Moreover, when a homoallylic acid was used, a radical cascade reaction took place with the formation of three C?C bonds.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 70918-54-6
Reference£º
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem