Computed Properties of C8H7NO3. Recently I am researching about TITANIUM(IV) OXIDE PHOTOCATALYST; VISIBLE-LIGHT; CHEMOSELECTIVE REDUCTION; REDUCIBLE GROUPS; DIOXIDE; AMMONIA; NANOPARTICLES; AMINOBENZENES; NITROARENES; SUSPENSION, Saw an article supported by the Japan Society for the Promotion of Science (JSPS)Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [17H03462, 17H04967, 18J12706]; Program for the Strategic Research Foundation at Private Universities 2014-2018 from MEXT; Kindai University; Faculty of Science and Engineering, Kindai University. Published in ELSEVIER in AMSTERDAM ,Authors: Fukui, M; Koshida, W; Tanaka, A; Hashimoto, K; Kominami, H. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
Since reduction and oxidation reactions simultaneously occur over a photocatalyst, a hole scavenger (a hydrogen source in the field of organic chemistry) is required to obtain a reduced product. The use of organic waste as the hole scavenger is environmentally favorable because the organic waste is degraded during the photocatalytic reduction. In this study, methylamine was used as the hole scavenger for photocatalytic reduction (hydrogenation) of nitrobenzenes over a titanium(IV) oxide photocatalyst. Corresponding anilines were obtained almost quantitatively at room temperature and under atmospheric pressure without the use of a precious metal and hydrogen gas. Nitrobenzenes having reducible functional groups such as chloro and acetyl groups were chemoselectively hydrogenated to corresponding anilines with the groups being preserved. Various parameters affecting the efficiency and the rate of the photocatalytic reaction are discussed on the basis of results of the physicochemical analyses.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem