Reference of 214894-89-0, New Advances in Chemical Research in 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. 214894-89-0, Name is 5-(Bromomethyl)-2,3-dihydro-1,4-benzodioxine. In a Article, once mentioned of 214894-89-0.
The reaction of different chloromethyl ethers 1 with an excess of lithium powder and a catalytic amount of 4,4?-di-tert-butylbiphenyl (2.5 mol %) in THF at 0 C leads to the corresponding alpha-lithiomethyl ether intermediates, through a chlorine-lithium exchange, which spontaneously undergo a clean [1,2]-Wittig rearrangement affording the expected homobenzylic alcohols 2. This is the first version of this rearrangement starting from easily available chloromethyl ethers.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 214894-89-0. You can get involved in discussing the latest developments in this exciting area about 214894-89-0